63765-03-7

Basic information

• Product Name: (1S,4S)-2-[benzylimino]-1,7,7-trimethylbicyclo[2.2.1]heptane
• CAS NO: 63765-03-7
• Molecular Weight: 241.376
• Mol File: 63765-03-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1S,4S)-2-[benzylimino]-1,7,7-trimethylbicyclo[2.2.1]heptane(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,4S)-2-[benzylimino]-1,7,7-trimethylbicyclo[2.2.1]heptane(63765-03-7)
• EPA Substance Registry System: (1S,4S)-2-[benzylimino]-1,7,7-trimethylbicyclo[2.2.1]heptane(63765-03-7)

Safety Data

• Hazardous Substances Data: 63765-03-7(Hazardous Substances Data)

Upstream product

• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 100-46-9 benzylamine 

Downstream Products

• 63797-18-2 2'-benzyl-1,7,7-trimethyl-spiro[bicyclo[2.2.1]heptane-2,3'-oxaziridine] 
• 1306602-63-0 R,R,R-N-benzyl-camphorammonium tris(pentafluorophenyl)hydridoborate 
• 158411-96-2 (1R,2R,4R)-N-benzyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine 
• 142508-10-9 benzyl-((1R)-bornyl)-amine 
• 63797-18-2 2'-benzyl-1,7,7-trimethyl-spiro[bicyclo[2.2.1]heptane-2,3'-oxaziridine] 
• 129704-13-8 (S)-2-amino-1,1,2-triphenylethanol 
• 122250-07-1 (R)-1,1,2-Triphenyl-2-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-ethanol 
• 122250-07-1 (S)-1,1,2-Triphenyl-2-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-ethanol 
• 174195-97-2 (S)-1-(1'-amino-1'-phenylmethyl)cyclohexanol 
• 122250-04-8 1-{(R)-Phenyl-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-methyl}-cyclohexanol 
• 122250-04-8 1-{(S)-Phenyl-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-methyl}-cyclohexanol 
• 530-36-9 (S)-2-Amino-1,2-diphenyl-ethanol 
• 122250-08-2 (S)-1,2-Diphenyl-2-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-ethanol 
• 122250-08-2 (R)-1,2-Diphenyl-2-[(1S,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-ethanol 

Relevant articles and documents

Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3

Reductions of chiral ketimines effected under H2 by catalytic amounts of B(C6F5)3 result in moderate to excellent diastereoselectivities. In the case of camphor and menthone derived imines, the reductions procee

ASYMMETRIC SYNTHESES IV: ENANTIOSELECTIVE SYNTHESIS OF (R)-BENZYLIC AMINES VIA ALKYLATION OF D-CAMPHOR KETIMINE

An efficient asymmetric synthesis of (R)-benzylic amines in optical purity 36-90percent had been achieved by alkylation of a chiral ketimine prepared from D-camphor and benzylamine.Diastereoselectivity in the alkylation is dependent on the alkyl halides.