63877-68-9Relevant articles and documents
The remarkable catalytic activity of ultra-small free-CeO2 nanoparticles in selective carbon-carbon bond formation reactions in water at room temperature
Banerjee, Subhash
supporting information, p. 5350 - 5353 (2015/07/07)
A simple and efficient protocol for selective bis-Michael addition and mono-allylation of active methylene compounds has been demonstrated using ultra-small (size ~5 nm) uncapped cerium oxide nanoparticles (free-CeO2 NPs) as a reusable catalyst in water at room temperature. The free-CeO2 NPs were characterized by powder XRD, TEM and XPS studies. Free-CeO2 NPs efficiently catalyzed both the reactions and produced good to excellent yields of products.
Superbasic sodium stannate as catalyst for dehydrogenation, Michael addition and transesterification reactions
Zhang, Shu-Guo,Wei, Yu-Dan,Yin, Shuang-Feng,Luo, Sheng-Lian,Au, Chak-Tong
experimental part, p. 113 - 118 (2012/03/09)
It has been shown that sodium stannate with superbasic sites generated on its surface can be obtained through simple thermal treatment of sodium stannate hydrate in pure N2. In this study, we analyzed the as-prepared materials using powder X-ray diffraction, X-ray photoelectron spectroscopy, and N2 physisorption methods. The superbasic sites were characterized by techniques of Hammett indicators and temperature-programmed desorption using CO2 as adsorbate. It was shown that after undergoing calcination at 623 K, there are ample superbasic sites on sodium stannate: up to 0.254 mmol/g. The superbasicity of the materials was further confirmed by employing the 1-hexene as well as cyclohexa-1,4-diene double bond isomerization reactions. The superbasicity is attributed to the higher electron-donating ability of surface O2-. The sodium stannate samples showed excellent catalytic efficiency towards selected reactions, namely the dehydrogenation of propa-2-nol, Michael addition of electron-deficient olefins, and transesterification of cyclic carbonate with methanol. It was observed that with rise of heat-treatment temperature from 573 to 623 K, both superbasicity and catalytic activity increased, reaching a maximum at 623 K, and then declined. It is deduced that catalytic efficiency is closely related to superbasicity of the sodium stannate catalysts.
STABILIZATION OF HYDROXYLAMINE CONTAINING SOLUTIONS AND METHOD FOR THEIR PREPARATION
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Page/Page column 18, (2009/05/28)
The invention relates to the use of amidoximes for prevention of or stabilization of hydroxylamine compounds against undesired decomposition.