63905-21-5

Basic information

• Product Name: 3-(Allyloxy)propane-1,2-diol diacetate
• Synonyms: 3-(Allyloxy)propane-1,2-diol diacetate;3-Allyloxy 1,2-propanediol diacetate
• CAS NO: 63905-21-5
• Molecular Formula: C10H16 O5
• Molecular Weight: 216.231
• Mol File: 63905-21-5.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 272.1°Cat760mmHg
• Flash Point: 113.8°C
• Appearance: /
• Density: 1.068g/cm³
• Vapor Pressure: 0.0062mmHg at 25°C
• Refractive Index: 1.44
• CAS DataBase Reference: 3-(Allyloxy)propane-1,2-diol diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(Allyloxy)propane-1,2-diol diacetate(63905-21-5)
• EPA Substance Registry System: 3-(Allyloxy)propane-1,2-diol diacetate(63905-21-5)

Safety Data

• Hazardous Substances Data: 63905-21-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H16O5/c1-4-5-13-6-10(15-9(3)12)7-14-8(2)11/h4,10H,1,5-7H2,2-3H3

Upstream product

• 557-40-4 Allyl ether 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 106-92-3 Allyl glycidyl ether 
• 100011-03-8 3-allyloxy-2-hydroxypropyl acetate 
• 75-05-8 acetonitrile 

Relevant articles and documents

Diacetoxylation of nonconjugated dienes with TeO2 and the isolation of intermediate organotellurium compounds

Tellurium(IV) oxide (TeO2) reacts with nonconjugated dienes in acetic acid at reflux temperature in the presence of lithium halide or iodine to give the corresponding vic-diacetates in moderate yields.When the reaction is carried out at 80 deg C and the reaction mixture is then reduced with aqueous sodium thiosulfate, bis(β-acetoxyalkyl)ditellurides are isolated as main products.Treatment of the ditellurides with refluxing acetic acid affords the corresponding vic-diacetates in good yields.The expected tellurium containing heterocyclic compounds, such as telluracyclopentanes and telluracyclohexanes, are not formed and/or isolated under the conditions employed.When 4-vinylcyclohexene and limonene are used as dienes in the diacetoxylation reaction, aromatic compounds due to the dehydrogenation of cyclohexene ring are also produced in moderate yields. Keywords: Tellurium; Oxidation; Diolefin; Lithium halide; Iodine; Diacetoxylation

Heterogeneous acidic and eco-friendly reagents for mild and convenient conversion of epoxides to 1,2-diacetates

A highly regioselective ring-opening of epoxides with acetic anhydride in the presence of hydrated disodium hydrogen phosphate and sodium hydrogen sulfate as efficient and eco-friendly reagents is described. The reactions are clean and lead to 1,2-diacetates in high to excellent yields.

Direct transformation of epoxides to 1,2-diacetates with Ac2O/B(OH)3 system

Direct transformation of different kinds of epoxides to 1,2-diacetates was carried out easily and efficiently with Ac2O/B(OH)3 system. All reactions were carried out under reflux conditions within 2 h to afford 1,2-diacetates in high yields.