63955-67-9

Basic information

• Product Name: 1H-Indole, 1-methyl-3-(phenylthio)-
• CAS NO: 63955-67-9
• Molecular Formula: C15H13NS
• Molecular Weight: 239.341
• Mol File: 63955-67-9.mol
• Article Data: 48

Chemical Properties

• CAS DataBase Reference: 1H-Indole, 1-methyl-3-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Indole, 1-methyl-3-(phenylthio)-(63955-67-9)
• EPA Substance Registry System: 1H-Indole, 1-methyl-3-(phenylthio)-(63955-67-9)

Safety Data

• Hazardous Substances Data: 63955-67-9(Hazardous Substances Data)

Upstream product

• 603-76-9 1-methylindole 
• 108-98-5 thiophenol 
• 14204-27-4 N-phenylthiophthalimide 
• 882-33-7 diphenyldisulfane 
• 128070-50-8 2-(phenyldisulfanyl)benzo[d]thiazole 
• 98-09-9 benzenesulfonyl chloride 
• 80-17-1 benzenesufonyl hydrazide 
• 873-55-2 sodium benzenesulfonate 
• 120-72-9 indole 
• 54491-43-9 3-phenylthioindole 
• 77-78-1 dimethyl sulfate 
• 618-41-7 Benzenesulfinic acid 
• 98-80-6 phenylboronic acid 
• 1193-82-4 racemic methyl phenyl sulfoxide 

Downstream Products

• 120-72-9 indole 
• 70291-88-2 2,3-bis-phenyl-sulphenylindole 
• 603-76-9 1-methylindole 
• 63955-64-6 1-methyl-2,3-bis(phenylthio)-1H-indole 
• 120517-32-0 1-methyl-2-(phenylsulfanyl)-1H-indole 
• 120517-31-9 5-chloro-2-(methylthio)-1H-indole 

Relevant articles and documents

Synergistic Effect of Squaric Acid in Bromine-Catalyzed Deoxygenation of Sulfonyl Derivatives: Mechanistic Investigations and Synthetic Applications in Electrophilic (Fluoroalkyl)sulfenylation

A method for electrophilic (fluoroalkyl)sulfenylation of nucleophiles by collaborative CTAB- and squaric acid-promoted deoxygenation of sulfonyl derivatives is reported. Mechanistic studies indicate that squaric acid dramatically decreased the energy barr

Triphosgene/Sodium Organosulfinate System: A General and Efficient Electrophilic Thiolation of Silylenol Ethers and Electron-Rich Heteroaromatics

An efficient and practical approach to electrophilic thiolation was developed by using commercially available triphosgene as a reductant and the appropriate alkyl- or arylsulfinates, which were transformed in situ into electrophilic RSCl intermediates in the presence of triphosgene. This procedure represents a general and powerful approach for the synthesis of α-(trifluoromethyl)thio-substituted ketones and thiolated electron-rich heteroaromatic compounds.

Switchable regioselection of C-H thiolation of indoles using different TMS counterions

A switchable regioselectivity in C-H thiolation reaction by simply swapping the counteranions of TMS is reported here for the first time. An exclusive C3-H thiolation of indoles with sodium arylsulfinates was achieved in the presence of TMSCl as a promoter. In contrast, with the use of TMSOTf instead of TMSCl under otherwise identical conditions, a regiospecific C2-H thiolation of indoles was realized with the same set of substrates.