6397-12-2

Basic information

• Product Name: 4-ethyl-3,4-dihydro-2H-benzo[b][1,4]thiazine
• CAS NO: 6397-12-2
• Molecular Weight: 179.286
• Mol File: 6397-12-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-ethyl-3,4-dihydro-2H-benzo[b][1,4]thiazine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-ethyl-3,4-dihydro-2H-benzo[b][1,4]thiazine(6397-12-2)
• EPA Substance Registry System: 4-ethyl-3,4-dihydro-2H-benzo[b][1,4]thiazine(6397-12-2)

Safety Data

• Hazardous Substances Data: 6397-12-2(Hazardous Substances Data)

Upstream product

• 6397-16-6 4-acetyl-2,3-dihydrobenzo-1,4-thiazine 

Relevant articles and documents

Novel nonmetal catalytic bidirectional selective reduction method of tertiary aromatic amide

The invention relates to a novel effective bidirectional selective environment-friendly method for hydrosilation reduction of tertiary aromatic amide and an organic silicon reagent. The method comprises the following steps: selecting a nonmetal catalytic system, and selectively preparing a secondary or tertiary organic amine compound by successively catalyzing tertiary aromatic amide and cheap PHMS or triethoxysilane under a mild condition. By adopting the method, the bidirectional selective reduction of the tertiary aromatic amide is realized by innovatively utilizing an electronic effect and steric hindrance difference of an organic silicon reagent at first time, so that a brand new strategy is provided for the reduction of amide and derivative of the amide, the defects of the traditional method that the substrate functional group is poor in compatibility, the production cost is high and the like can be overcome, and the application prospect of the amine compound prepared in industrial production or laboratory is promising.