64020-33-3

Basic information

• Product Name: 5-Hexen-2-one, 1-phenyl-
• Synonyms: benzyl 3-butenyl ketone;1-phenyl-hex-5-en-2-one;5-Hexen-2-one,1-phenyl;1-Phenyl-5-hexen-2-one;1-Phenyl-5-hexen-2-on;3-butenyl benzyl ketone
• CAS NO: 64020-33-3
• Molecular Formula: C12H14O
• Molecular Weight: 174.243
• Mol File: 64020-33-3.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 263.7±9.0 °C(Predicted)
• Density: 0.965±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 5-Hexen-2-one, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hexen-2-one, 1-phenyl-(64020-33-3)
• EPA Substance Registry System: 5-Hexen-2-one, 1-phenyl-(64020-33-3)

Safety Data

• Hazardous Substances Data: 64020-33-3(Hazardous Substances Data)

Upstream product

• 75-01-4 chloroethylene 
• 101-97-3 Ethyl 2-phenylethanoate 
• 80945-30-8 2-(trimethylsilylmethyl)-1-(1-oxo-2-phenylethyl)cyclopropane 
• 103-79-7 1-phenyl-acetone 
• 122-78-1 phenylacetaldehyde 
• 5729-65-7 1-phenyl-5-hexene-2-ol 
• 591-80-0 pent-4-enoic acid 
• 154045-29-1 1-Imidazol-1-yl-pent-4-en-1-one 
• 1539-57-7 diethyl 2,6-dimethyl-4-benzyl-1,4-dihydropyridine-3,5-dicarboxylate 
• 95091-90-0 N-methoxy-N-methyl-4-pentenamide 
• 6921-34-2 benzylmagnesium chloride 
• 1589-82-8 phenylmagnesium bromide 
• 58170-51-7 1-(4-morpholinyl)-4-penten-1-one 
• 57918-71-5 1-Phenyl-2-propanone Potassium Enolate 

Downstream Products

• 5729-65-7 1-phenyl-5-hexene-2-ol 
• 90-43-7 2-Phenylphenol 
• 941598-60-3 (+/-)-N-benzyl-N'-(1-benzyl-penten-4-yl)-sulfamide 
• 1444-65-1 (RS)-2-phenylcyclohexanone 
• 32776-14-0 1-phenyl-hexane-2,5-dione 

Relevant articles and documents

Synthesis of Oxa-Bridged Medium-Sized Carbocyclic Rings via Prins Cyclization

Herein, we report a new method for the synthesis of oxa-bridged carbocyclic units based on intramolecular Prins reaction of dioxinones. Our new synthetic approach is flexible and practical and has been successfully applied to the preparation of highly fun

Light-Driven Carbene Catalysis for the Synthesis of Aliphatic and α-Amino Ketones

Single-electron N-heterocyclic carbene (NHC) catalysis has gained attention recently for the synthesis of C?C bonds. Guided by density functional theory and mechanistic analyses, we report the light-driven synthesis of aliphatic and α-amino ketones using single-electron NHC operators. Computational and experimental results reveal that the reactivity of the key radical intermediate is substrate-dependent and can be modulated through steric and electronic parameters of the NHC. Catalyst potential is harnessed in the visible-light driven generation of an acyl azolium radical species that undergoes selective coupling with various radical partners to afford diverse ketone products. This methodology is showcased in the direct late-stage functionalization of amino acids and pharmaceutical compounds, highlighting the utility of single-electron NHC operators.

Copper(II) carboxylate promoted intramolecular diamination of terminal alkenes: Improved reaction conditions and expanded substrate scope

The copper(II) carboxylate promoted diamination reaction has been improved by the use of the organic soluble copper(II) neodecanoate [Cu(ND)2]. Cu(ND)2 allowed the less-polar solvent dichloroethane (DCE) to be used, and as a consequence, decomposition of less-reactive substrates could be avoided. High diastereoselectivity was observed in the synthesis of 2,5-disubstituted pyrrolidines. Ureas, bis(anllines), and α-amido pyrroles derived from 2-allylaniline could also participate in the diamination reaction.