64275-76-9Relevant articles and documents
Selective conversion of enol ethers into alcohols in the presence of alkenes using Hg(OAc)2-NaBH4
Crouch, R. David,Mehlmann, John F.,Herb, Brian R.,Mitten, Jeffrey V.,Dai, H. George
, p. 559 - 561 (2007/10/03)
Alkyl enol ethers derived from aldehydes undergo selective oxymercuration-demercuration with aqueous Hg(OAc)2-NaBH4 in the presence of an alkene in good to excellent yield. This method allows the survival of mono-, trans and cis di-, and tri-substituted alkenes as well as cyclic alkenes.
Synthesis of (Z)-6-heneicosen-11-one, (+/-)(Z)-14-methyl-8-hexadecen-1-ol and (+/-)-5,6-dehydrosenedigitalene
Sharma, M. L.,Verma, Sadhana,Chand, Tek
, p. 1030 - 1034 (2007/10/03)
Three naturally occurring compounds (Z)-6-heneicosen-11-one (1), (+/-)-(Z)-14-methyl-8-hexadecen-1-ol (2) and (+/-)-5,6-dehydrosenedigitalene (3) have been synthesised using lithium tetrachlorocuperate catalysed coupling reaction.
Free-radical cyclizations promoted by allylic O-stannyl ketyls: The intramolecular coupling of the β-carbons of activated alkenes
Enholm, Eric J.,Kinter, Kevin S.
, p. 7784 - 7785 (2007/10/02)
-
