64362-19-2

Basic information

• Product Name: 1,4-Epoxynaphthalene-2,3-dicarboxylic acid, 1,4-dihydro-1,4-diphenyl-, dimethyl ester
• CAS NO: 64362-19-2
• Molecular Formula: C26H20O5
• Molecular Weight: 412.442
• Mol File: 64362-19-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,4-Epoxynaphthalene-2,3-dicarboxylic acid, 1,4-dihydro-1,4-diphenyl-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Epoxynaphthalene-2,3-dicarboxylic acid, 1,4-dihydro-1,4-diphenyl-, dimethyl ester(64362-19-2)
• EPA Substance Registry System: 1,4-Epoxynaphthalene-2,3-dicarboxylic acid, 1,4-dihydro-1,4-diphenyl-, dimethyl ester(64362-19-2)

Safety Data

• Hazardous Substances Data: 64362-19-2(Hazardous Substances Data)

Upstream product

• 5471-63-6 1,3-diphenylisobenzofuran 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 34082-81-0 8-Oxo-1,9-diphenyl-12-oxa-tricyclo[7.2.1.0^2,7]dodeca-2⁽⁷⁾,3,5,10-tetraene-10,11-dicarboxylic acid dimethyl ester 

Downstream Products

• 64362-20-5 dimethyl 1-oxo-2,4-diphenyl-1,2-dihydronaphthalene-2,3-dicarboxylate 
• 83164-99-2 dimethyl 1,4-diphenylnaphthalene-2,3-dicarboxylate 

Relevant articles and documents

Regioselective arene homologation through rhenium-catalyzed deoxygenative aromatization of 7-oxabicyclo[2.2.1]hepta-2,5-dienes

Combined use of oxorhenium catalysts with triphenyl phosphite as an oxygen acceptor allowed efficient deoxygenative aromatization of oxabicyclic dienes. The reaction proceeded under neutral conditions and was compatible with various functional groups. Combining this deoxygenation with regioselective bromination and trapping of the generated aryne with furan resulted in benzannulative π-extension at the periphery of the PAHs. This enabled direct use of unfunctionalized PAHs for extension of π-conjugation. Iteration of the transformations increased the number of fused-benzene rings one at a time, which has the potential to alter the properties of PAHs by fine-tuning the degree of π-conjugation, shape, and edge topology.

Phototransformations of Epoxyindanone Adducts. Steady-State and Laser Flash Photolysis Studies

The phototransformations of several cycloadducts of 2,3-diphenyl-2,3-epoxy-1-indanone are reported.All these substrates exhibited singlet-state-mediated transformations leading to benzoxocinones, whereas in some cases, depending on the substituents presen

COMPARATIVE INVESTIGATION OF THE REACTIVITY OF ETHYLENIC AND ACETYLENIC DIENOPHILES IN THE DIELS-ALDER REACTION

The reactivity of substituted phencyclones, anthracenes, and a series of other dienes in the Diels-Alder reaction with dimethyl fumarate, dimethyl acetylenedicarboxylate, 1-hexene, and 1-hexyne and with certain monosubstituted ethylenic and acetylenic die