644964-56-7

Basic information

• Product Name: Boronic acid, [4-[[(9-anthracenylmethyl)amino]carbonyl]phenyl]-
• CAS NO: 644964-56-7
• Molecular Formula: C22H18BNO3
• Molecular Weight: 355.19400
• Mol File: 644964-56-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Boronic acid, [4-[[(9-anthracenylmethyl)amino]carbonyl]phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Boronic acid, [4-[[(9-anthracenylmethyl)amino]carbonyl]phenyl]-(644964-56-7)
• EPA Substance Registry System: Boronic acid, [4-[[(9-anthracenylmethyl)amino]carbonyl]phenyl]-(644964-56-7)

Safety Data

• Hazardous Substances Data: 644964-56-7(Hazardous Substances Data)

Upstream product

• 195133-98-3 9-(azidomethyl)anthracene 
• 2417-77-8 9-bromoethylanthracene 
• 1468-95-7 9-hydroxymethylanthracene 
• 2476-68-8 9-(aminomethyl)anthracene 
• 14047-29-1 4-carboxyphenylboronic acid 

Relevant articles and documents

Polymer-Assisted Solution-Phase (PASP) Suzuki Couplings Employing an Anthracene-Tagged Palladium Catalyst

A general method for polymer-assisted solution-phase (PASP) Suzuki reactions employing a combination of anthracene-tagged palladium catalyst and anthracene-tagged boronic acid with a polymer-supported carbonate base is reported. The anthracene-tagged catalyst allows for the easy removal of the Pd catalyst along with the dissociated phosphine ligand and phosphine oxide byproducts by sequestration through a chemoselective Diels-Alder reaction with a maleimide resin. The polymer-supported carbonate base facilitates the removal of excess boronic acid and the borane-containing byproducts present at the end of the coupling reaction. The Suzuki coupling reaction can be efficiently conducted by using combinations of the anthracene-tagged Pd catalyst, polymer-supported carbonate base, and anthracene-tagged boronic acid to yield the desired product in high purity and yield without the use of chromatography.