64502-98-3

Basic information

• Product Name: 2,6-di-tert-butyl-4-methyl-1-deuteriophenol
• Synonyms: 2,6-di-tert-butyl-4-methyl-1-deuteriophenol
• CAS NO: 64502-98-3
• Molecular Weight: 221.347
• Mol File: 64502-98-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,6-di-tert-butyl-4-methyl-1-deuteriophenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-di-tert-butyl-4-methyl-1-deuteriophenol(64502-98-3)
• EPA Substance Registry System: 2,6-di-tert-butyl-4-methyl-1-deuteriophenol(64502-98-3)

Safety Data

• Hazardous Substances Data: 64502-98-3(Hazardous Substances Data)

Upstream product

• 128-37-0 2,6-di-tert-butyl-4-methyl-phenol 

Downstream Products

• 6858-01-1 2,6-di-tert-butyl-4-methylphenoxy radical 
• 171562-99-5 Sm(OC(=C₆H₅D)Ph)2(O-C₆H₂-(t)Bu₂-2,6-Me-4)(hexamethylphosphoramide)2 
• 719-22-2 2,6-Di-tert-butyl-1,4-benzoquinone 
• 7722-84-1 dihydrogen peroxide 
• 151898-14-5 Zr(CH₂C(CH₃)3)3(OC₆H₂(CH₃)(C(CH₃)3)2) 

Relevant articles and documents

A Mononuclear Non-heme Manganese(III)-Aqua Complex as a New Active Oxidant in Hydrogen Atom Transfer Reactions

A mononuclear non-heme Mn(III)-aqua complex, [(dpaq)MnIII(OH2)]2+ (1, dpaq = 2-[bis(pyridin-2-ylmethyl)]amino-N-quinolin-8-yl-acetamidate), is capable of conducting hydrogen atom transfer (HAT) reactions much more efficiently than the corresponding Mn(III)-hydroxo complex, [(dpaq)MnIII(OH)]+ (2); the high reactivity of 1 results from the positive one-electron reduction potential of 1 (Ered vs SCE = 1.03 V), compared to that of 2 (Ered vs SCE = -0.1 V). The HAT mechanism of 1 varies between electron transfer followed by proton transfer and one-step concerted proton-coupled electron transfer, depending on the one-electron oxidation potentials of substrates. To the best of our knowledge, this is the first example showing that metal(III)-aqua complex can be an effective H-atom abstraction reagent.