64537-28-6

Basic information

• Product Name: Rh(CO)(NO)Cl₂(P(C₆H₅)3)2
• CAS NO: 64537-28-6
• Molecular Weight: 756.41
• Mol File: 64537-28-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Rh(CO)(NO)Cl₂(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: Rh(CO)(NO)Cl₂(P(C₆H₅)3)2(64537-28-6)
• EPA Substance Registry System: Rh(CO)(NO)Cl₂(P(C₆H₅)3)2(64537-28-6)

Safety Data

• Hazardous Substances Data: 64537-28-6(Hazardous Substances Data)

Upstream product

• 15318-33-9 chlorocarbonylbis(triphenylphosphine)rhodium(I) 
• 17185-29-4 carbonylhydridetris(triphenylphosphine)rhodium(I) 

Downstream Products

• 17185-29-4 carbonylhydridetris(triphenylphosphine)rhodium(I) 

Relevant articles and documents

Rhodium Nitrosyl Complexes

The reactions of nitrosyl chloride and nitrosyl bromide with rhodium(I) complexes containing triphenylphosphine and triphenylarsine have been studied.These reactions result in the formation of the complexes of the type (X = Cl, Br; L = PPh3, AsPh3) and Rh(NO)X3L2.Reactions of Rh(CO)(NO)ClX(PPh3)2 (X = Cl, Br) with hydrazine hydrate afford PhH(CO)(PPh3)3 and a highly hygroscopic red complex X (X = Cl or Br).The probable structures of these complexes have been proposed on the basis of elemental analyses, spectroscopic (IR, UV and EPR) and magnetic data.