64677-34-5

Basic information

• Product Name: Propanedioic acid, (2-oxo-2-phenylethylidene)-, dimethyl ester
• CAS NO: 64677-34-5
• Molecular Formula: C13H12O5
• Molecular Weight: 248.235
• Mol File: 64677-34-5.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, (2-oxo-2-phenylethylidene)-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, (2-oxo-2-phenylethylidene)-, dimethyl ester(64677-34-5)
• EPA Substance Registry System: Propanedioic acid, (2-oxo-2-phenylethylidene)-, dimethyl ester(64677-34-5)

Safety Data

• Hazardous Substances Data: 64677-34-5(Hazardous Substances Data)

Upstream product

• 3298-40-6 mesoxalate de methyle 
• 20913-05-7 (Benzoylmethylene)triphenylphosphorane 
• 115852-13-6 methyl 2-methoxy-5-phenyl-furan-3-carboxylate 
• 126835-47-0 methyl 1-methoxy-5-phenyl-2,3,7-trioxabicyclo<2.2.1>hept-5-ene-6-carboxylate 
• 109-92-2 ethyl vinyl ether 
• 103-71-9 phenyl isocyanate 
• 107-29-9 Acetaldehyde oxime 
• 100-64-1 cyclohexanone-oxime 
• 613-91-2 acetophenone oxime 
• 352-93-2 diethyl sulphide 
• 218794-58-2 benzophenone oxide O-<1-hydroperoxy-3,3-(dimethoxycarbonyl)-1-phenyl-2-propenyl> ether 
• 574-66-3 Benzophenone oxime 
• 932-90-1 Benzaldoxime 
• 1129-37-9 4-nitrobenzaldehyde oxime 

Downstream Products

• 54011-17-5 2-(2-Oxo-2-phenyl-1-phenylamino-ethylidene)-malonic acid dimethyl ester 
• 76003-67-3 5-Benzoyl-1-methyl-1,5-dihydro-[1,2,3]triazole-4,4-dicarboxylic acid dimethyl ester 
• 76003-71-9 5-Benzoyl-1-benzyl-1,5-dihydro-[1,2,3]triazole-4,4-dicarboxylic acid dimethyl ester 
• 76003-79-7 2-(1-Diazo-2-oxo-2-phenyl-ethyl)-2-phenylamino-malonic acid dimethyl ester 
• 76003-69-5 5-Benzoyl-1-phenyl-1,5-dihydro-[1,2,3]triazole-4,4-dicarboxylic acid dimethyl ester 
• 104504-62-3 5-benzoyl-4,4'-dimethoxycarbonyl-1-(4'methylbenzyl)-1,2,3-triazoline 

Relevant articles and documents

Electrocatalytic Activation of Donor–Acceptor Cyclopropanes and Cyclobutanes: An Alternative C(sp3)?C(sp3) Cleavage Mode

We describe the first electrochemical activation of D–A cyclopropanes and D–A cyclobutanes leading after C(sp3)?C(sp3) cleavage to the formation of highly reactive radical cations. This concept is utilized to formally insert molecula

Regioselective oxidative ring-opening of cyclopropenyl carboxylates by visible light photoredox catalysis

Catalyzed by Ir(dFCF3ppy)2(dtbbpy)PF6, several aroyl methylidenemalonates were synthesized in good to excellent yields via visible light photoredox-catalyzed the oxidative ring-opening of cyclopropenyl carboxylate derivatives. The possible mechanism of oxidative quenching cycle was proposed.