6472-58-8Relevant articles and documents
Solid state synthesis of ring-substituted aminobenzenesulphonic acids
Kapoor, Inder Pal Singh,Kapoor, Manisha,Singh, Gurdip
experimental part, p. 1556 - 1560 (2011/02/23)
Treatment of 2-methoxyaniline and 3,5-dichloroaniline with conc.H 2SO4 in 2:1 molar ratio at RT affords the corresponding sulphate salts. These salts have been characterized by X-ray diffraction and spectral analyses. Both these salts are found to form ring substituted aminobenzenesulphonic acids in solid state, via proton transfer, under thermal and microwave irradiations.
Sulfonation of arylamines Part 9 - Solid state synthesis of di-ortho ring substituted aminobenzenesulfonic acids
Singh, Gurdip,Kapoor, Inder Pal Singh,Singh, Jyotsna
, p. 1114 - 1117 (2007/10/03)
Di-ortho ring substituted arylammonium sulfates (Di-o-RSAS) have been prepared from the corresponding arylamines by treatment with conc. H2SO4 and characterized by elemental, gravimetric and spectral analyses. These sulfates yield the corresponding ring substituted aminobenzenesulfonic acids (RSABSA) when subjected to thermal energy. Non-isothermal gravimetric studies on di-o-RSAS support the formation of RSABSA. It is observed that most of the salts undergo transformation to acid in solid state via proton transfer reaction prior to sulfonation.