64788-85-8

Basic information

• Product Name: Silane, dimethylphenyl[(1E)-2-phenylethenyl]-
• CAS NO: 64788-85-8
• Molecular Formula: C16H18Si
• Molecular Weight: 238.404
• Mol File: 64788-85-8.mol
• Article Data: 85

Chemical Properties

• CAS DataBase Reference: Silane, dimethylphenyl[(1E)-2-phenylethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, dimethylphenyl[(1E)-2-phenylethenyl]-(64788-85-8)
• EPA Substance Registry System: Silane, dimethylphenyl[(1E)-2-phenylethenyl]-(64788-85-8)

Safety Data

• Hazardous Substances Data: 64788-85-8(Hazardous Substances Data)

Upstream product

• 66003-76-7 Diphenyliodonium triflate 
• 1125-26-4 dimethylphenylvinylsilane 
• 766-77-8 Dimethylphenylsilane 
• 536-74-3 phenylacetylene 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 79628-15-2 dimethyl(phenyl)(phenylethynyl)silane 
• 15436-06-3 (E)-β-(methylthio)styrene 
• 100-42-5 styrene 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 768-33-2 phenyldimethylsilyl chloride 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 6783-05-7 trans-2-phenylvinylboronic acid 
• 64788-84-7 β-(Z)-2-dimethylphenylsilylstyrene 
• 1261157-96-3 [2-(dimethylphenylsilyl)-2-phenylethyl]diphenylphosphane oxide 

Downstream Products

• 59873-86-8 (E)-4-methyl-1-phenylpenta-1,4-dien-3-one 
• 3988-77-0 2-cinnamoylthiophene 
• 3160-32-5 (1E)-4-methyl-1-phenylpent-1-en-3-one 
• 538-44-3 (E)-benzylidenepinacolone 
• 84642-43-3 (E)-1-phenylhepta-1,6-dien-3-one 
• 3152-68-9 (1E)-1-phenylpent-1-en-3-one 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 22966-19-4 trans-4'-methoxychalcone 
• 200010-90-8 dimethyl(phenyl)[2-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethyl]silane 
• 1440972-07-5 (R)-dimethyl(phenyl)(2-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethyl)silane 
• 1896-62-4 (E)-benzalacetone 
• 122-78-1 phenylacetaldehyde 
• 42599-24-6 E-styryl iodide 
• 103-30-0 (E)-1,2-diphenyl-ethene 

Relevant articles and documents

Silsesquioxyl rhodium(i) complexes - Synthesis, structure and catalytic activity

The first bi- and mononuclear rhodium(i) complexes [{Rh(μ-OSi 8O12(i-Bu)7)(cod)}2] (5), [Rh(cod)(PCy3)(OSi8O12(i-Bu)7)] (6) with a hindered hepta(iso-butyl)silsesquiox

Caged Iridium Catalyst for Hydrosilylation of Alkynes with High Site Selectivity

The proximity and orientation of the reacting groups can be different in organic cages from in free solution, thus affecting the selectivity of the reaction. Herein, we reported a synthetic strategy to encapsulate iridium nanoparticles (Ir-NP@COP1-T) within organic cages in the homogeneous solution. Ir-NP@COP1-T showed good selectivity in the hydrosilylation reaction of alkynes. Our work provides a new perspective to the catalysis field by using soluble microporous cages as support for inorganic nano particles.

Direct Access to α,β-Unsaturated Ketones via Rh/MgCl2-Mediated Acylation of Vinylsilanes

We report herein the facile and practical construction of α,β-unsaturated ketones via rhodium-catalyzed direct acylation of vinylsilanes with readily available and abundant carboxylic acids. This protocol features access to a diverse array of synthetically useful functionalities with moderate to excellent yields. More importantly, the late-stage functionalization of pharmaceuticals was also realized with synthetically useful yield.