64984-68-5

Basic information

• Product Name: Benzene, 1,4-bis(2-bromoethenyl)-, (E,E)-
• CAS NO: 64984-68-5
• Molecular Formula: C10H8Br2
• Molecular Weight: 287.982
• Mol File: 64984-68-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, 1,4-bis(2-bromoethenyl)-, (E,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,4-bis(2-bromoethenyl)-, (E,E)-(64984-68-5)
• EPA Substance Registry System: Benzene, 1,4-bis(2-bromoethenyl)-, (E,E)-(64984-68-5)

Safety Data

• Hazardous Substances Data: 64984-68-5(Hazardous Substances Data)

Upstream product

• 77295-67-1 1,4-bis(2,2-dibromoethenyl)benzene 
• 260365-75-1 C₂₆H₃₀Si₂ 
• 623-27-8 terephthalaldehyde, 
• 23713-85-1 1,4-phenylenediacrylic acid 
• 88248-71-9 2,3,2',3'-tetrabromo-3,3'-p-phenylene-di-propionic acid 
• 16323-43-6 1,4-phenylenediacrylic acid 

Downstream Products

• 1202570-62-4 (E,E)-4'-(2-bromoethenyl)-2,5-dioctyloxystilbene 
• 60916-94-1 (E,E)-1,4-bis[2-(thiophen-2-yl)-ethenyl]benzene 
• 1608-41-9 1,4-distyrylbenzene 
• 54842-61-4 (E,E)-1,4-bis[2-(4-methoxyphenyl)-ethenyl]benzene 
• 64984-75-4 C₂₀H₁₈ 

Relevant articles and documents

Nickel(II)-magnesium-catalyzed cross-coupling of 1,1-dibromo-1-alkenes with diphenylphosphine oxide: One-pot synthesis of (E)-1-alkenylphosphine oxides or bisphosphine oxides

A novel nickel(II)-magnesium-mediated cross-coupling of diphenylphosphine oxide with a variety of 1,1-dibromo-1-alkenes has been developed, which provides a powerful and general methodology for the stereoselective synthesis of various (E)-1-alkenylphosphine oxides or bisphosphine oxides, with operational simplicity of the procedure, good to high yields and broad substrate applicability. Mechanistic studies reveal that the reaction might involve a Hirao reduction, cross-coupling and Michael addition. Copyright

Stereoselective synthesis of (E)-β-arylvinyl bromides by microwave-induced Hunsdiecker-type reaction

(E)-β-Arylvinyl bromides were readily prepared in a short reaction time (1-2 min) by microwave irradiation of the corresponding 3-arylpropenoic acids in the presence of N-bromosuccinimide and a catalytic amount of lithium acetate. Furthermore, two facile strategies for the efficient synthesis of (E)-β-bromo-4-arylethynylstyrene and (E)-β-bromo-4-arylstyrene have been developed by respectively combining Sonogashira and Suzuki coupling reaction with Hunsdiecker-type reaction. Formation of cis-α-bromo-β- lactone by microwave irradiation of cis-cinnamic acid with NBS provides a useful support for the mechanistic study of the present halodecarboxylation reaction. Georg Thieme Verlag Stuttgart.