65025-95-8

Basic information

• Product Name: 4-(T-BUTYLDI-ME-SIO-ME)HEXA-H-5-(T-H-PYR AN -2-YLOXY)-CYCLOPENTA(B)FURAN-2-ON, 97
• Synonyms: 4-(T-BUTYLDI-ME-SIO-ME)HEXA-H-5-(T-H-PYR AN -2-YLOXY)-CYCLOPENTA(B)FURAN-2-ON, 97;(3aR,4S,5R,6aS)-(?-(tert-Butyldimethylsilyloxymethyl)hexahydro-5-(tetrahydro-2H-pyran-2-yloxy)-2H-cyclopenta[b]furan-2-one;4-(T-butyldi-me-sio-me)hexa-H-5-(T-H-pyran -2-ylo;(3aR,4S,5R,6aS)-(-)-(tert-Butyldimethylsilyloxymethyl)hexahydro-5-(tetrahydro-2H-pyran-2-yloxy)-2H-cyclopenta[b]furan-2-one;(3aR,4S,5R,6aS)-4-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]methyl]hexahydro-5-[(tetrahydro-2H-pyran-2-yl)oxy]-2H-cyclopenta[b]furan-2-one;2H-Cyclopenta[b]furan-2-one,4-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]hexahydro-5-[(tetrahydro-2H-pyran-2-yl)oxy]-,(3aR,4S,5R,6aS)-;(3aR,4S,5R,6aS)-4-(tert-Butyldimethylsilyloxy)methyl-5-tetrahydropyranyloxy-hexahydro-2H-cyclopenta[b]furan-2-one;[3aR-(3aα,4α,5β,6aα)]-4-[[[(1,1-DiMethylethyl)diMethylsilyl]oxy]Methyl]hexahydro-5-[(tetrahydro-2H-pyran-2-yl)oxy]-2H-cyclopenta[b]furan-2-on
• CAS NO: 65025-95-8
• Molecular Formula: C₁₉H₃₄O₅Si
• Molecular Weight: 370.55576
• EINECS: 1312995-182-4
• Product Categories: Chiral Reagents;Heterocycles;Intermediates & Fine Chemicals;Pharmaceuticals
• Mol File: 65025-95-8.mol
• Article Data: 12

Chemical Properties

• Melting Point: 40-53 °C(lit.)
• Flash Point: 113 °C
• Appearance: /
• Density: 1.07
• Refractive Index: 1.488
• Storage Temp.: 2-8°C
• Solubility: Acetone, Chloroform, Dichloromethane, Ethyl Acetate, Methanol
• CAS DataBase Reference: 4-(T-BUTYLDI-ME-SIO-ME)HEXA-H-5-(T-H-PYR AN -2-YLOXY)-CYCLOPENTA(B)FURAN-2-ON, 97(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(T-BUTYLDI-ME-SIO-ME)HEXA-H-5-(T-H-PYR AN -2-YLOXY)-CYCLOPENTA(B)FURAN-2-ON, 97(65025-95-8)
• EPA Substance Registry System: 4-(T-BUTYLDI-ME-SIO-ME)HEXA-H-5-(T-H-PYR AN -2-YLOXY)-CYCLOPENTA(B)FURAN-2-ON, 97(65025-95-8)

Safety Data

• Hazardous Substances Data: 65025-95-8(Hazardous Substances Data)

Usage

Uses

Intermediate in the preparation of prostaglandin derivatives

InChI:InChI=1/C19H34O5Si/c1-19(2,3)25(4,5)22-12-14-13-10-17(20)23-15(13)11-16(14)24-18-8-6-7-9-21-18/h13-16,18H,6-12H2,1-5H3/t13-,14-,15+,16-,18?/m1/s1

Upstream product

• 32233-40-2 (3aR,4S,5R,6aS)-5-hydroxy-4-(hydroxymethyl)hexahydro-2H-cyclopenta[b]furan-2-one 
• 110-87-2 3,4-dihydro-2H-pyran 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 62939-82-6 (3aR,4S,5R,6aS)-5-(acetyloxy)-4-[(acetyloxy)methyl]hexahydro-2H-cyclopenta[b]furan-2-one 
• 26054-46-6 (-)-(1S,5R)-2-oxabicyclo[3.3.0]oct-6-en-3-one 
• 288-32-4 1H-imidazole 
• 69222-61-3 2-oxo-6-syn-(hydroxymethyl)-7-anti-(tetrahydropyran-2-yloxy)-cis-bicyclo<3.3.0>octan-3-one 
• 62447-84-1 (3aR,4S,5S,6R,6aR)-4-Benzyloxymethyl-6-iodo-5-(tetrahydro-pyran-2-yloxy)-hexahydro-cyclopenta[b]furan-2-one 
• 31767-37-0 6-Benzyloxymethyl-7-hydroxy-8-iodo-2-oxabicyclo<3.3.0>octan-3-one 
• 32233-38-8 3α,5α-dihydroxy-2β-(benzyloxymethyl)cyclopentane-1α-acetic acid γ-lactone 3-tetrahydropyran-2-yl ether 
• 165876-61-9 (3aR,4S,5R,6aS)-4-((tert-butyldimethylsilyloxy)methyl)-2-oxo hexahydro-2H-cyclopenta[b]furan-5-yl biphenyl-4-carboxylate 
• 31752-99-5 (-)-Corey lactone 5-(4-phenylbenzoate) 
• 58707-50-9 (3aR,4S,5R,6aS)-4-((tert-butyldimethylsilyloxy)methyl)-5-hydroxyhexahydro-2H-cyclopenta[b]furan-2-one 

Downstream Products

• 87224-46-2 (3aR,4S,5R,6aS)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-phenylselanyl-5-(tetrahydro-pyran-2-yloxy)-hexahydro-cyclopenta[b]furan-2-one 
• 86255-65-4 (3aR,5S,6aR)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3a-phenylselanyl-5-(tetrahydro-pyran-2-yloxy)-hexahydro-cyclopenta[b]furan-2-one 
• 32233-40-2 (3aR,4S,5R,6aS)-5-hydroxy-4-(hydroxymethyl)hexahydro-2H-cyclopenta[b]furan-2-one 
• 67788-45-8 (1S,5R,6S,7R)-7-(tetrahydropyran-2-yl)oxy-6-(tetrahydropyran-2-yl)oxymethyl-2-oxabicyclo[3.3.0]octan-3-one 
• 88911-35-7 (+)-9(O)-methano-Δ^6(9α)-PGI₁ 
• 88931-51-5 isocarbacyclin 
• 142102-19-0 <1S-(1α,2β,3α)>-2-<2-<<(tert-butyldimethylsilyl)oxy>methyl>-5-methenyl-3-(tetrahydropyranyloxy)cyclopentanyl>ethanol triphenylmethyl ether 
• 142066-65-7 <1S-(1α,2β,3α,5α)>-2-<2-<<(tert-butyldimethylsilyl)oxy>methyl>-5-<<(methylsulfonyl)oxy>methyl>-3-(tetrahydropyranyloxy)cyclopentanyl>ethanol triphenylmethyl ether 
• 77540-95-5 Benzoic acid (1S,2R,3S,4S)-2-(1,2-dihydroxy-ethyl)-4-hydroxy-3-((E)-3-hydroxy-oct-1-enyl)-cyclopentyl ester 
• 77540-96-6 Benzoic acid (1S,2S,3S,4S)-2-formyl-4-hydroxy-3-((E)-3-hydroxy-oct-1-enyl)-cyclopentyl ester 
• 77540-93-3 Benzoic acid (1R,2R,3S,4R)-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-3-hydroxymethyl-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester 
• 77540-97-7 Benzoic acid (1R,2R,3R,4R)-2-((Z)-6-carboxy-hex-1-enyl)-4-hydroxy-3-((E)-3-hydroxy-oct-1-enyl)-cyclopentyl ester 
• 77540-98-8 Benzoic acid (1S,2S,3S,4S)-4-hydroxy-3-((E)-3-hydroxy-oct-1-enyl)-2-((Z)-6-methoxycarbonyl-hex-1-enyl)-cyclopentyl ester 
• 77540-92-2 Benzoic acid (1S,2S,3R,4S)-3-(tert-butyl-dimethyl-silanyloxymethyl)-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-4-(tetrahydro-pyran-2-yloxy)-cyclopentyl ester 

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