65108-32-9

Basic information

• Product Name: Benzenemethanol, a-(1,1-dimethyl-2-propynyl)-
• CAS NO: 65108-32-9
• Molecular Formula: C12H14O
• Molecular Weight: 174.243
• Mol File: 65108-32-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(1,1-dimethyl-2-propynyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(1,1-dimethyl-2-propynyl)-(65108-32-9)
• EPA Substance Registry System: Benzenemethanol, a-(1,1-dimethyl-2-propynyl)-(65108-32-9)

Safety Data

• Hazardous Substances Data: 65108-32-9(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 78-80-8 2-methylbut-1-en-3-yne 
• 6214-31-9 3-bromo-3-methylbut-1-yne 
• 1111-97-3 3-chloro-3-methylbut-1-yne 
• 6214-32-0 1-bromo-3-methylbuta-1,2-diene 
• 598-25-4 Dimethylallene 

Relevant articles and documents

Sequential Catalytic Annulations: Divergent Synthesis of Heterocycles through a Radical [1,4]-Oxygen Shift

A radical [1,4]-oxygen-atom transfer has been realized by the reaction of linear alkyne-tethered ketoximes and ethynylbenziodoxolones (EBX) under sequential catalytic conditions. Mechanism studies indicate that the O atom transfer experiences a cascade O atom radical cyclization/alkynylation/N–O bond photocleavage and subsequent N,O-diradical rearrangement. By the diversification of catalytic sequences, a series of structurally important 3H-pyrrol-3-ones and chlorinated furo[3,2-b]pyrroles are divergently synthesized along with an O atom shift under the catalysis of Cu/Ir photosensitization and Cu/Ir photosensitization/AlCl3, respectively.

Assessment of the activity of 8'diphenylphosphino-8'-methoxy-1,1'- binaphthyl as a ligand for palladium-catalyzed reactions

A monodentate phosphine, 8-diphenylphosphino-8'-methoxy-1,1'-binaphthyl, was shown to be active as a ligand in palladium-catalyzed reactions, including the reduction of allylic carbonates with formic acid, hydrosilylation of a terminal olefin, and hydroboration of but-1-en-3-yne, even though it has a highly hindered lone pair.

A CONVENIENT PREPARATION OF BENZYLIC HOMOPROPARGYLIC ALCOHOLS VIA ALLENYLLITHIUM REAGENTS

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