65115-51-7

Basic information

• Product Name: Silane, trimethyl(tricyclo[3.3.1.1(3,7)]dec-2-yloxy)-
• Synonyms: Silane, trimethyl(tricyclo[3.3.1.1(3,7)]dec-2-yloxy)-
• CAS NO: 65115-51-7
• Molecular Formula: C₁₃H₂₄OSi
• Molecular Weight: 0
• Mol File: 65115-51-7.mol
• Article Data: 41

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Silane, trimethyl(tricyclo[3.3.1.1(3,7)]dec-2-yloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(tricyclo[3.3.1.1(3,7)]dec-2-yloxy)-(65115-51-7)
• EPA Substance Registry System: Silane, trimethyl(tricyclo[3.3.1.1(3,7)]dec-2-yloxy)-(65115-51-7)

Safety Data

• Hazardous Substances Data: 65115-51-7(Hazardous Substances Data)

Upstream product

• 18243-21-5 trimethylsilyl formate 
• 700-57-2 1-adamantanol 
• 1058649-54-9 C₁₂H₂₀O₂ 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 1058649-56-1 2-(ethoxymethoxy)adamantane 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 700-57-2 1-adamantanol 
• 700-58-3 2-Adamantanone 
• 16668-83-0 2-fluoroadamantane 

Relevant articles and documents

Use of Silylated Formiates as Hydrosilane Equivalents

The present invention relates to a method for preparing organic compounds of formula (I) by reaction between a silylated formiate of formula (II) and an organic compound in the presence of a catalyst and optionally of an additive. The invention also relates to use of the method for preparing organic compounds of formula (I) for the preparation of reagents for fine chemistry and for heavy chemistry, as well as in the production of vitamins, pharmaceutical products, adhesives, acrylic fibres, synthetic leathers, and pesticides.

Nanoporous Na+-montmorillonite perchloric acid as an efficient and recyclable catalyst for the chemoselective protection of hydroxyl groups

Nanoporous Na+-montmorillonite perchloric acid as a novel heterogeneous reusable solid acid catalyst was easily prepared by treatment of Na+-montmorillonite as a cheap and commercially available support with perchloric acid. The catalyst was characterized using a variety of techniques including X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), energy dispersive X-ray spectroscopy (EDX), pH analysis and determination of the Hammett acidity function. The prepared reagent showed excellent catalytic activity for the chemoselective conversion of alcohols and phenols to their corresponding trimethylsilyl ethers with 1,1,1,3,3,3-hexamethyldisilazane (HMDS) at room temperature. Deprotection of the resulting trimethylsilyl ethers can also be carried out using the same catalyst in ethanol. All reactions were performed under mild and completely heterogeneous reaction conditions in good to excellent yields. The notable advantages of this protocol are: short reaction times, high yields, availability and low cost of the reagent, easy work-up procedure and the reusability of the catalyst during a simple filtration.

Graphene oxide-bound electron-deficient tin(IV) porphyrin: a highly efficient and selective catalyst for trimethylsilylation of alcohols and phenols with hexamethyldisilazane

The catalytic activity of graphene oxide-bound tetrakis(p-aminophenyl)porphyrinatotin(IV) trifluoromethanesulfonate, [SnIV(TNH2PP)(OTf)2], in the trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) is reported. The prepared catalyst was characterized using inductively coupled plasma analysis, scanning electron microscopy, transmission electron microscopy, and Fourier transform infrared and diffuse reflectance UV–visible spectroscopies. This heterogeneous catalyst was used for selective trimethylsilylation of various alcohols and phenols with HMDS in short reaction times and high yields. Also, the catalyst is of high reusability and stability, in that it was recovered several times without loss of its initial activity. The chemoselectivity of this catalytic system in the silylation of primary alcohols in the presence of secondary and tertiary alcohols and also phenols was investigated.