65118-17-4

Basic information

• Product Name: Benzenesulfonamide, 2-nitro-N-2-propenyl-
• CAS NO: 65118-17-4
• Molecular Formula: C9H10N2O4S
• Molecular Weight: 242.255
• Mol File: 65118-17-4.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, 2-nitro-N-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, 2-nitro-N-2-propenyl-(65118-17-4)
• EPA Substance Registry System: Benzenesulfonamide, 2-nitro-N-2-propenyl-(65118-17-4)

Safety Data

• Hazardous Substances Data: 65118-17-4(Hazardous Substances Data)

Upstream product

• 198572-71-3 N-(tert-butoxycarbonyl)-2-nitrobenzenesulfonamide 
• 908072-33-3 2-nitro-N-(prop-2-yn-1-yl)benzene-1-sulfonamide 
• 1694-92-4 2-Nitrobenzenesulfonyl chloride 
• 107-11-9 1-amino-2-propene 

Downstream Products

• 945492-88-6 C₂₃H₄₁N₃O₅SSi 
• 945493-34-5 C₂₃H₄₁N₃O₅SSi 
• 945492-93-3 (2R,S)-2-[N-allyl-3-(4-benzyloxyphenyl)propanamido]-N-[(2S)-1-(N-allyl-o-nitrophenylsulfonamido)-5-triisopropylsilyloxypentan-2-yl]-5-triisopropylsilyloxypentanamide 
• 945492-94-4 (2R,S)-2-[N-allyl-3-(4-benzyloxyphenyl)propanamido]-N-[(2R)-1-(N-allyl-o-nitrophenylsulfonamido)-5-triisopropylsilyloxypentan-2-yl]-5-triisopropylsilyloxypentanamide 
• 945492-95-5 (2S)-2-[N-allyl-3-(4-benzyloxyphenyl)acetamido]-N-[(2S)-1-(N-allyl-o-nitrophenylsulfonamido)-5-triisopropylsilyloxypentan-2-yl]-5-triisopropylsilyloxypentanamide 
• 945492-96-6 (2R)-2-[N-allyl-3-(4-benzyloxyphenyl)acetamido]-N-[(2S)-1-(N-allyl-o-nitrophenylsulfonamido)-5-triisopropylsilyloxypentan-2-yl]-5-triisopropylsilyloxypentanamide 
• 945492-98-8 (2R)-2-[N-allyl-3-(4-benzyloxyphenyl)acetamido]-N-[(2R)-1-(N-allyl-o-nitrophenylsulfonamido)-5-triisopropylsilyloxypentan-2-yl]-5-triisopropylsilyloxypentanamide 
• 945492-97-7 (2S)-2-[N-allyl-3-(4-benzyloxyphenyl)acetamido]-N-[(2R)-1-(N-allyl-o-nitrophenylsulfonamido)-5-triisopropylsilyloxypentan-2-yl]-5-triisopropylsilyloxypentanamide 
• 945492-99-9 (2S,5S,6E)-2,5-bis[3-(triisopropylsilyloxy)propyl]-1-[3-(4-benzyloxyphenyl)propionyl]-7-(o-nitrobenzenesulfonyl)-1,4,7-triazacycloundec-9-en-3-one 
• 945493-00-5 (2R,5S,6E)-2,5-bis[3-(triisopropylsilyloxy)propyl]-1-[3-(4-benzyloxyphenyl)propionyl]-7-(o-nitrobenzenesulfonyl)-1,4,7-triazacycloundec-9-en-3-one 
• 945493-02-7 (2R,5R,6E)-2,5-bis[3-(triisopropylsilyloxy)propyl]-1-[3-(4-benzyloxyphenyl)propionyl]-7-(o-nitrobenzenesulfonyl)-1,4,7-triazacycloundec-9-en-3-one 
• 945493-01-6 (2S,5R,6E)-2,5-bis[3-(triisopropylsilyloxy)propyl]-1-[3-(4-benzyloxyphenyl)propionyl]-7-(o-nitrobenzenesulfonyl)-1,4,7-triazacycloundec-9-en-3-one 
• 945493-03-8 (2S,5S,6E)-2,5-bis[3-(triisopropylsilyloxy)propyl]-1-(4-benzyloxyphenylacetyl)-7-(o-nitrobenzenesulfonyl)-1,4,7-triazacycloundec-9-en-3-one 
• 945493-04-9 (2R,5S,6E)-2,5-bis[3-(triisopropylsilyloxy)propyl]-1-(4-benzyloxyphenylacetyl)-7-(o-nitrobenzenesulfonyl)-1,4,7-triazacycloundec-9-en-3-one 

Relevant articles and documents

Twofold Radical-Based Synthesis of N, C-Difunctionalized Bicyclo[1.1.1]pentanes

Bicyclo[1.1.1]pentylamines (BCPAs) are of growing importance to the pharmaceutical industry as sp3-rich bioisosteres of anilines and N-tert-butyl groups. Here we report a facile synthesis of 1,3-disubstituted BCPAs using a twofold radical functionalization strategy. Sulfonamidyl radicals, generated through fragmentation of α-iodoaziridines, undergo initial addition to [1.1.1]propellane to afford iodo-BCPAs; the newly formed C-I bond in these products is then functionalized via a silyl-mediated Giese reaction. This chemistry also translates smoothly to 1,3-disubstituted iodo-BCPs. A wide variety of radical acceptors and iodo-BCPAs are accommodated, providing straightforward access to an array of valuable aniline-like isosteres.

Consecutive Aminolithiation-Carbolithiation of a Linear Aminoalkene Bearing Terminal Vinyl Sulfide Moiety to Give Hydro-indolizine

Aminolithiation-carbolithiation tandem cyclization of an aminoalkene bearing vinyl sulfide moiety proceeded smoothly using stoichiometric amounts of BuLi. Both aminolithiation and carbo-lithiation were in equilibrium at room temperature, and the stereoche

An Enantioselective Cascade Cyclopropanation Reaction Catalyzed by Rhodium(I): Asymmetric Synthesis of Vinylcyclopropanes

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