65133-99-5

Basic information

• Product Name: Benzene, (4-methylhexyl)-, (S)-
• CAS NO: 65133-99-5
• Molecular Formula: C13H20
• Molecular Weight: 176.302
• Mol File: 65133-99-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, (4-methylhexyl)-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (4-methylhexyl)-, (S)-(65133-99-5)
• EPA Substance Registry System: Benzene, (4-methylhexyl)-, (S)-(65133-99-5)

Safety Data

• Hazardous Substances Data: 65133-99-5(Hazardous Substances Data)

Upstream product

• 6839-54-9 (S)-(+)-4-Methyl-1-phenyl-1-hexanon 
• 6860-46-4 (4S)-4-methylhexanoyl chloride 
• 534-00-9 (S)-2-methylbutyl bromide 
• 1730-89-8 (S)-4-methylhexanoic acid 
• 14371-10-9 (E)-3-phenylpropenal 
• 6210-82-8 diethyl S-(+)-2-methyl-1-butyl malonate 

Downstream Products

• 78976-07-5 trans-(S,S)-(-)-2,2'-Bis(4-methylhexyl)azobenzol 
• 78976-06-4 cis-(S,S)-(-)-2,2'-Bis(4-methylhexyl)azobenzol 
• 78976-09-7 trans-(S,S)-(+)-4,4'-Bis(4-methylhexyl)azobenzol 
• 78976-08-6 cis-(S,S)-(+)-4,4'-Bis(4-methylhexyl)azobenzol 
• 78976-20-2 (S)-(+)-1-(4-Methylhexyl)-4-nitrobenzol 
• 78976-18-8 (S)-(+)-1-(4-Methylhexyl)-2-nitrobenzol 

Relevant articles and documents

Asymmetric Traceless Petasis Borono-Mannich Reactions of Enals: Reductive Transposition of Allylic Diazenes

The traceless Petasis borono-Mannich reaction of enals, sulfonylhydrazines, and allylboronates, catalyzed by chiral biphenols, results in an asymmetric reductive transposition of the in situ generated allylic diazene. Acyclic 1,4-diene products bearing either alkyl- or aryl-substituted benzylic stereocenters are afforded in excellent yields and enantiomeric ratios of up to 99:1. The use of crotylboronates in the reaction results in concomitant formation of two stereocenters in either a 1,4-syn or anti relationship from the corresponding E- or Z-crotylboronate used in the reaction. The use of β-monosubstituted enals in the asymmetric traceless Petasis borono-Mannich reaction of crotylboronates installs tertiary methyl-bearing stereocenters in good yields and high enantioselectivities.