65136-45-0

Basic information

• Product Name: N-methyl-2-ethylindole
• Synonyms: N-methyl-2-ethylindole
• CAS NO: 65136-45-0
• Molecular Formula: C₁₁H₁₃N
• Molecular Weight: 159
• Mol File: 65136-45-0.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-methyl-2-ethylindole(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-2-ethylindole(65136-45-0)
• EPA Substance Registry System: N-methyl-2-ethylindole(65136-45-0)

Safety Data

• Hazardous Substances Data: 65136-45-0(Hazardous Substances Data)

Upstream product

• 95-20-5 2-methyl-1H-indole 
• 74-88-4 methyl iodide 
• 40899-68-1 1-(methoxymethyl)-1H-indole 
• 97-94-9 triethyl borane 
• 100-52-7 benzaldehyde 
• 603-76-9 1-methylindole 
• 626-55-1 3-Bromopyridine 
• 122135-83-5 ethyl 2-trifluoromethanesulfonyloxycyclohex-1-enecarboxylate 
• 201230-82-2 carbon monoxide 
• 77412-96-5 1-trifluoromethanesulfonyloxy-4-t-butylcyclohexene 
• 619-44-3 methyl 4-iodobenzoate 
• 42599-24-6 E-styryl iodide 
• 589-87-7 1,4-bromoiodobenzene 
• 624-31-7 4-tolyl iodide 

Relevant articles and documents

A novel C-C bond formation reaction with 1-methoxymethylindolylborate

The reaction of 1-methoxymethylindolylborates 2 with electrophiles in the presence of benzaldehyde enabled the novel construction of tri-substituted indoles in a 'one-pot' procedure.

VINYLOXYBORANE PROMOTED 1,4-ADDITION OF TRIETHYL(1-METHYLINDOL-2-YL)BORATE TO 2-CYCLOALKENONES

The conjugate addition reaction of triethyl(1-methylindol-2-yl)borate to 2-cycloalkenone could be effected with a catalytic amount of vinyloxyborane.

Novel Aspects on the Reaction of Trialkyl-(1-methylindol-2-yl)borates

A new use of trialkyl-(1-methylindol-2-yl)borates for the synthesis of 2-substituted indoles involving the palladium catalysed cross-coupling with vinylic and aromatic halides, or a facile alkyl migration from boron to carbon without an additional electrophile is described.