653-96-3

Basic information

• Product Name: anthranilic acid-(2,2,2-trifluoro-ethyl ester)
• Synonyms: anthranilic acid-(2,2,2-trifluoro-ethyl ester)
• CAS NO: 653-96-3
• Molecular Weight: 219.163
• Mol File: 653-96-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: anthranilic acid-(2,2,2-trifluoro-ethyl ester)(CAS DataBase Reference)
• NIST Chemistry Reference: anthranilic acid-(2,2,2-trifluoro-ethyl ester)(653-96-3)
• EPA Substance Registry System: anthranilic acid-(2,2,2-trifluoro-ethyl ester)(653-96-3)

Safety Data

• Hazardous Substances Data: 653-96-3(Hazardous Substances Data)

Upstream product

• 86451-26-5 2,2'-(phenyl-λ³-iodanediyl)bis(isoindoline-1,3-dione) 
• 136918-14-4 phthalimide 
• 75-89-8 2,2,2-trifluoroethanol 
• 118-48-9 isatoic anhydride 

Downstream Products

• 75-89-8 2,2,2-trifluoroethanol 
• 118-92-3 anthranilic acid 

Relevant articles and documents

Hofmann-type rearrangement of imides by in situ generation of imide-hypervalent iodines(III) from iodoarenes

The Hofmann-type rearrangement of aromatic and aliphatic imides using a hypervalent iodine(III) reagent generated in situ from PhI, m-CPBA, and TsOH·H2O proceeded in the presence of a base in alcohol to provide anthranilic acid derivatives and amino acid derivatives in high yields, respectively. This reaction proceeds through a tandem reaction via alcoholysis followed by a Hofmann rearrangement promoted by the formation of an imide-λ3-iodane intermediate.