653568-86-6

Basic information

• Product Name: Pt(^tBu₂bpy)Ph₂
• CAS NO: 653568-86-6
• Molecular Weight: 617.693
• Mol File: 653568-86-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt(^tBu₂bpy)Ph₂(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(^tBu₂bpy)Ph₂(653568-86-6)
• EPA Substance Registry System: Pt(^tBu₂bpy)Ph₂(653568-86-6)

Safety Data

• Hazardous Substances Data: 653568-86-6(Hazardous Substances Data)

Upstream product

• 72914-19-3 4,4'-di-tert-butyl-2,2'-bipyridine 

Downstream Products

• 309758-46-1 (4,4'-di-tert-butyl-2,2'-bipyridine)Pt(Cl)(Ph) 
• 653569-00-7 [Pt(O₂CCF₃)Ph(4,4'-di-tert-butyl-2,2'-bipyridine)] 
• 653568-99-1 [Pt(CF₃SO₃)Ph(4,4'-di-tert-butyl-2,2'-bipyridine)] 
• 653568-88-8 [PtHClPh₂(4,4'-di-tert-butyl-2,2'-bipyridine)] 
• 1450898-46-0 C₂₆H₂₉F₆N₃O₄PtS₂ 
• 653569-02-9 [PtHCl₂Ph(4,4'-di-tert-butyl-2,2'-bipyridine)] 
• 1349082-55-8 [(4,4'-di-tert-butyl-2,2'-bipyridyl)Pt(Ph)(NCMe)][B(3,5-bis(trifluoromethyl)phenyl)4] 
• 1044510-82-8 [(^tbpy)₂Pt(Ph)(thf)][B(3,5-(CF₃)₂C₆H₃)₄] 
• 1286744-69-1 (4,4'-di-tert-butyl-2,2'-dipyridyl)Pt(Ph)2(I)2 

Relevant articles and documents

The mechanism of protonolysis of phenylplatinum(II) bonds in complexes with phenyl trans to nitrogen or carbon donors

Addition of acids of the form HX (X = Cl, BF4, CF 3SO3, CF3CO2) to complexes [PtPh2(NN)] (NN = bu2bpy = 4,4′-di-ferf-butyl-2, 2′-bipyridine) and [PtPh(NCN)] (NCN = 2,6-C6H 3(CH2NMe2)2) at -78°C gave the corresponding phenyl(hydrido)platinum(IV) complexes [PtX(H)Ph2(NN)] and [PtX(H)Ph(NCN)], which decomposed by reductive elimination of benzene at about -20°C to give the platinum(II) complexes [PtXPh(NN)] and [PtX(NCN)]. Further addition of HCl to [PtClPh(NN)] at low temperature gave [PtHCl 2Ph(NN)], which decomposed above -10°C, to give benzene and [PtCl2(NN)]. The reaction of DBF4 in the presence of excess CD3OD with [PtPh2(NN)] led to formation of C 6H5D and C6H4D2 but with [PtPh(NCN)] no multiple deuterium incorporation was observed in the product benzene. The mechanisms of these reactions are discussed.