65398-69-8

Basic information

• Product Name: 3,4-DIMETHYLTHIOANISOLE
• Synonyms: 3,4-DIMETHYLTHIOANISOLE
• CAS NO: 65398-69-8
• Molecular Formula: C₉H₁₂S
• Molecular Weight: 152.26
• Mol File: 65398-69-8.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,4-DIMETHYLTHIOANISOLE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-DIMETHYLTHIOANISOLE(65398-69-8)
• EPA Substance Registry System: 3,4-DIMETHYLTHIOANISOLE(65398-69-8)

Safety Data

• Hazardous Substances Data: 65398-69-8(Hazardous Substances Data)

Upstream product

• 18800-53-8 3,4-dimethylthiophenol 
• 1073-14-9 4,4-dimethylcyclohexa-2,5-dienone 
• 3908-55-2 Trimethyl(methylthio)silane 
• 77-78-1 dimethyl sulfate 
• 371-15-3 p-fluorothioanisole 
• 74-88-4 methyl iodide 

Downstream Products

• 38417-53-7 1,2-dimethyl-4-(methylsulfinyl)benzene 
• 74-87-3 methylene chloride 
• 18800-53-8 3,4-dimethylthiophenol 
• 123159-38-6 2,3,6,7-Tetramethyl-9,10-dithia-4b,9a-diphospha-indeno[1,2-a]indene 
• 22884-95-3 3,4-dimethylbenzonitrile 
• 37734-36-4 4,5-dimethyl-benzene-1,2-dithiol 
• 65398-68-7 Thiocarbonic acid S-(4,5-dimethyl-2-methylsulfanyl-phenyl) ester O-methyl ester 

Relevant articles and documents

Novel dienone-phenol type rearrangement of 4,4-disubstituted cyclohexadienone system using thiosilane

Thiosilane and a catalytic amount of a Bronsted acid mediate the novel domino-type rearrangement reaction of the 4,4-disubstituted cyclohexadienones to produce the 3,4-disubstituted benzenethioethers; the key step is 1,2-addition of thiosilane to dienone.

The Reaction of Alkyl-substituted Thioanisoles with PCl3 and AlCl3: a Route to Benzothiadiphospholobenzothiadiphosphole Derivatives

The synthesis of benzothiadiphospholobenzothiadiphosphole derivatives starting from alkyl-substituted thioanisoles and PCl3-AlCl3 is reported.The reaction is carried out at reflux in the absence of solvent and the yields are dependent on the starting sulphide.These new heterocycles can be purified by simple filtration on a Florisil column and have been characterized by 1H-, 13C-, (1H)31P-n.m.r. and mass spectroscopy analyses.New unexpected findings are also described.