65488-27-9

Basic information

• Product Name: Benzoic acid, 4-(trimethylstannyl)-, methyl ester
• CAS NO: 65488-27-9
• Molecular Formula: C11H16O2Sn
• Molecular Weight: 298.957
• Mol File: 65488-27-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-(trimethylstannyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-(trimethylstannyl)-, methyl ester(65488-27-9)
• EPA Substance Registry System: Benzoic acid, 4-(trimethylstannyl)-, methyl ester(65488-27-9)

Safety Data

• Hazardous Substances Data: 65488-27-9(Hazardous Substances Data)

Upstream product

• 1126-46-1 Methyl 4-chlorobenzoate 
• 1066-45-1 trimethyltin(IV)chloride 
• 610-96-8 methyl chlorobenzoate 
• 661-69-8 hexamethyldistannane 
• 3795-79-7 methyl 4-(methylthio)benzoate 
• 6302-65-4 methyl 4-mercaptobenzoate 
• 7377-26-6 4-Methoxycarbonylbenzoyl chloride 
• 709-69-3 methyl 4-(fluorocarbonyl) benzoate 
• 619-45-4 4-methoxycarbonyl aniline 
• 120579-20-6 methyl 4-((diethoxyphosphoryl)oxy)benzoate 
• 619-44-3 methyl 4-iodobenzoate 

Downstream Products

• 720-75-2 methyl 4-phenylbenzoate 
• 1132711-33-1 methyl 4-(7-bromo-5,6-benzo[c][1,2,5]thiadiazol-4-yl)benzoate 
• 153881-22-2 N-[2-(2-Amino-ethoxy)-ethyl]-4-(2-hydroxy-4-phenyl-cyclohexyl)-benzamide 
• 197777-76-7 4-(2-Hydroxy-4-phenyl-cyclohexyl)-benzoic acid 
• 153881-23-3 4-(4-Phenyl-cyclohex-1-enyl)-benzoic acid methyl ester 

Relevant articles and documents

Synthesis of Arylstannanes via Palladium-Catalyzed Decarbonylative Coupling of Aroyl Fluorides

Aryl stannanes are valuable precursors in organic transformations, but their synthetic methods are limited. Here we present a Pd-catalyzed decarbonylative stannylation of acid fluorides in the absence of exogenous base. Various aryl stannanes were efficiently prepared from bench-stable transition metal catalyst and ligand with broad functional group compatibility and substrate scope including natural products and pharmaceuticals. This protocol was also successfully used to a late-stage diversification of an existing uricosuric drug probenecid. (Figure presented.).

Synthesis of Aryl Trimethylstannane via BF3·OEt2-Mediated Cross-Coupling of Hexaalkyl Distannane Reagent with Aryl Triazene at Room Temperature

BF3·OEt2-mediated cross-coupling of (SnMe3)2 with aryl triazene offers a new strategy for the synthesis of aryl stannane. A variety of synthetically useful aryl trimethylstannanes were produced in moderate to good yields with this metal-free approach. One-pot sequential Stille cross-coupling with different aryl bromides provides a short entry to both symmetrical and unsymmetrical biaryl compounds.

Dye compounds, and their use in dye-sensitized solar cells

Disclosed are compounds of formula D-B-A-ANC (wherein D is an electron donor group, B is a chromophore group, A is an electron acceptor group, and ANC is an anchoring part comprising at least one anchoring group, and dye-sensitized solar cells (DSSC) incorporating the same as a dye-sensitizer.