655249-87-9

Basic information

• Product Name: AMIMNTF2
• Synonyms: AMIMNTF2;1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ;1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide >=98.5% (HPLC);1-Allyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide;bis(trifluoromethylsulfonyl)azanide:1-methyl-3-prop-2-enylimidazol-1-ium
• CAS NO: 655249-87-9
• Molecular Formula: C₂F₆NO₄S₂*C₇H₁₁N₂
• Molecular Weight: 403.3217592
• EINECS: 200-144-5
• Mol File: 655249-87-9.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• Density: 1.494 (29°C)
• Refractive Index: 1.4320 to 1.4360
• Storage Temp.: Inert atmosphere,Room Temperature
• CAS DataBase Reference: AMIMNTF2(CAS DataBase Reference)
• NIST Chemistry Reference: AMIMNTF2(655249-87-9)
• EPA Substance Registry System: AMIMNTF2(655249-87-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 655249-87-9(Hazardous Substances Data)

Usage

Description

AMIMNTF2, also known as 1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, is an ionic liquid with unique properties such as high thermal stability, low melting point, and excellent solvation ability. It is composed of an allyl-methylimidazolium cation and a bis(trifluoromethylsulfonyl)imide anion, making it a promising candidate for various applications in different industries.

Uses

Used in Energy Storage Industry:
AMIMNTF2 is used as an electrolyte for AMIMTFSI-propylene carbonate based electrolyte, which has potential applications in lithium-ion batteries. Its high thermal stability and excellent solvation ability make it a suitable candidate for improving the performance and safety of lithium-ion batteries.
Used in Chemical Separation Process:
AMIMNTF2 is used in the alkanes/alkenes separation process, where it acts as a selective solvent to separate these hydrocarbons. Its unique solvation properties enable efficient separation of alkanes and alkenes, which is crucial in the petrochemical industry.
Used in Nanotechnology:
AMIMNTF2 is used as a surface protector to develop luminescent silicon nanoparticles. Its ability to form stable complexes with silicon nanoparticles helps in enhancing their luminescent properties and stability, making them suitable for applications in optoelectronics and sensing devices.

Conductivity

8.871 mS/cm (30 °C)

Upstream product

• 31410-07-8 3-allyl-1-methyl-1H-imidazol-3-ium bromide 
• 90076-65-6 bis(trifluoromethane)sulfonimide lithium 
• 65039-07-8 N-allyl-N'-methylimidazolium iodide 
• 90076-67-8 potassium bis(trifluoromethylsulfonyl)imide 
• 65039-10-3 1-allyl-3-methylimidazolium chloride 

Relevant articles and documents

Synthesis and characterization of nitrogen-based ionic liquids bearing allyl groups and examples of their application

The syntheses and full spectral (NMR, MS, and IR), thermal (DSC) and ion chromatographic characterization of two series of amine-derived ionic liquids bearing allyl substituents and having chloride or bis(trifluoromethanesulfonyl)amide anions have been presented. The analysis of the dependence of the 1H NMR chemical shift values of the selected protons on the cation and anion structure has been conducted. DSC analysis records together with ion chromatography analysis results have been presented and interpreted. Moreover, a selection of obtained chloride ionic liquids have been transformed into the corresponding chlorocobaltates and chlorozincates or used as substrates in thiol-ene click reactions to indicate their potential as precursors of catalysts or various surface modifiers.

Dimethyldioxirane (DMDO) as a valuable oxidant for the synthesis of polyfunctional aromatic imidazolium monomers bearing epoxides

Conventional organic salts represent a new paradigm in many areas of research. Despite their great potential, an improvement in their physicochemical properties requires the chemical modification of their intrinsic structure. Thus, an efficient pathway was developed for the preparation of polyfunctional imidazolium monomers incorporating aromatic rings and terminal epoxides which presented a real synthetic challenge. In this work, we describe the reactivity of various oxidizing agents to develop a strong, clean and powerful methodology to generate epoxidized salts. Various reaction conditions for the formation of the epoxides were investigated such as the role of the cation and the counterion as well as the influence of an aromatic and/or aliphatic linker chain. Finally, we have evaluated the thermal properties of these new polyfunctional salts by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC).

Bifunctional hydrophobic ionic liquids: Facile synthesis by thiol-ene "click" chemistry

We describe the facile, robust and orthogonal fabrication of a structurally comprehensive library of hydrophobic trimethoxysilyl-functionalized ionic liquids with C7-C15 thioether spacer, using thiol-ene "click" chemistry. The synthesized ionic liquids displayed very low glass transition temperatures, high thermal stability and were hydrophobic in character. And the ability to serve as surface coating agents was tested by immobilizing them on the surface of iron oxide supermagnetic nanoparticles and the organic loadings were quantified.