65737-44-2

Basic information

• Product Name: Cyclohexanone, 2-(2-methyl-1-propenyl)-
• CAS NO: 65737-44-2
• Molecular Formula: C10H16O
• Molecular Weight: 152.236
• Mol File: 65737-44-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-(2-methyl-1-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-(2-methyl-1-propenyl)-(65737-44-2)
• EPA Substance Registry System: Cyclohexanone, 2-(2-methyl-1-propenyl)-(65737-44-2)

Safety Data

• Hazardous Substances Data: 65737-44-2(Hazardous Substances Data)

Upstream product

• 1588925-62-5 C₁₀H₁₈O 
• 14845-52-4 7-Oxo-1,1-dimethyl-spiro<2.5>octan 
• 3017-69-4 2-methyl-1-propenylbromide 
• 1424-22-2 1-cyclohexenyl acetate 

Relevant articles and documents

1-ALKENYLATION ON α-POSITION OF KETONE: PALLADIUM-CATALYZED REACTION OF TIN ENOLATES AND 1-BROMO-1-ALKENES

The reaction of tributyltin enolates, prepared from tributyltin methoxide and enol acetates in situ, with 1-bromo-1-alkenes in the presence of a catalytic amount of PdCl2(o-tolyl3P)2 was found to give the derivatives of allyl ketone in good yields.

Arylation and 1-Alkenylation on α-Position of Ketones via Tributyltin Enolates Catalyzed by Palladium Complex

The reaction of tributyltin enolates, prepared from tributyltin methoxide and enol acetates in situ, with aryl and 1-alkenyl bromides in the presence of dichlorobis(tri-o-tolylphosphine)palladium was found to give α-aryl and α-(1-alkenyl) ketones, respectively, in good yields with essentially complete retention of the enol acetate regiochemistry.