659726-12-2Relevant articles and documents
Enantioselective Access to 2,7-Cis-Disubstituted Oxepanes: Formal Synthesis of (+)-Isolaurepan
Carreno, M. Carmen,Des Mazery, Renaud,Urbano, Antonio,Colobert, Francoise,Solladie, Guy
, p. 297 - 299 (2004)
(Matrix presented) The asymmetric synthesis of 2,7-cis-disubstituted oxepanes bearing a sulfoxide is achieved from commercially available precursors in only five steps. The key step is the highly diastereoselective Et 3SiH/TMSOTf-promoted reduc