66050-82-6

Basic information

• Product Name: (2R)-methylhexyl (S)-α-methoxy-α-trifluoromethylphenylacetate
• Synonyms: (2R)-methylhexyl (S)-α-methoxy-α-trifluoromethylphenylacetate
• CAS NO: 66050-82-6
• Molecular Weight: 332.363
• Mol File: 66050-82-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R)-methylhexyl (S)-α-methoxy-α-trifluoromethylphenylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (2R)-methylhexyl (S)-α-methoxy-α-trifluoromethylphenylacetate(66050-82-6)
• EPA Substance Registry System: (2R)-methylhexyl (S)-α-methoxy-α-trifluoromethylphenylacetate(66050-82-6)

Safety Data

• Hazardous Substances Data: 66050-82-6(Hazardous Substances Data)

Upstream product

• 20445-31-2 R-(+)-α-trifluoromethyl-α-methoxy-phenylacetic acid 
• 624-22-6 (2S)-2-methyl-1-hexanol 
• 141022-82-4 (S)-(+)-4-isopropyl-3-hexanoyl-2-oxazolidinone 

Relevant articles and documents

Advances and Setbacks in the Total Synthesis of the Fungal Metabolite Curvicollide C: Synthesis and Elaboration of Non-Aldol Stereotriads from Gosteli-Type Allyl Vinyl Ethers

Advances and setbacks are reported in regard to the asymmetric total synthesis of the fungal metabolite curvicollide C relying on a synthetic strategy that exploits non-aldol stereotriads as chiral building blocks. A catalytic asymmetric Gosteli-Claisen rearrangement, a two-step aldehyde-to-alkyne-homologation, and a Julia-Kocienski olefination served as key C/C-connecting transformations.