66166-25-4Relevant articles and documents
Synthesis and Application of Heterocyclic Germatranes via Rhodium-Catalyzed Directed C?H Activation/Annulation with Alkynyl Germatranes and Palladium-Catalyzed Cross-Coupling
Xu, Meng-Yu,Wang, Chao,Jiang, Wei-Tao,Xiao, Bin
, p. 1706 - 1711 (2020)
Rhodium-catalyzed C?H activation and annulation with alkynyl germatranes for the synthesis of heterocyclic germatranes is described. Various heterocyclic germatranes were constructed by this protocol and applied in multiple derivatizations such as palladi
A convenient synthesis of 1,4-disubstituted isoquinolines by reactions of α-substituted 2-lithio-β-methoxystyrenes with nitriles
Kobayashi, Kazuhiro,Hayashi, Kazutaka,Miyamoto, Kazuna,Morikawa, Osamu,Konishi, Hisatoshi
, p. 2934 - 2938 (2008/02/05)
It has been found that halogen-lithium exchange between α-substituted 2-bromo-β-methoxystyrene derivatives and n-butyllithium generates α-substituted 2-lithio-β-methoxystyrene derivatives, which successfully react with a range of nitriles to afford the co
New synthesis of isoquinoline derivatives by reactions of 2-(2-methoxyethenyl)benzonitriles with organolithiums and lithium dialkylamides
Kobayashi, Kazuhiro,Shiokawa, Taiyo,Morikawa, Osamu,Konishi, Hisatoshi
, p. 236 - 237 (2007/10/03)
A simple and efficient synthesis of 1-alkyl(or aryl)isoquinoline and isoquinolin-1-amine derivatives based on intramolecular cyclization of 2-(2-methoxyethenyl)benzonitriles initiated by the addition of alkyl(or aryl)lithiums and lithium dialkylamides to the nitrile carbons, respectively, is described.