66192-11-8

Basic information

• Product Name: Propanedioic acid, [(2-bromophenyl)methyl]-, diethyl ester
• CAS NO: 66192-11-8
• Molecular Formula: C14H17BrO4
• Molecular Weight: 329.191
• Mol File: 66192-11-8.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, [(2-bromophenyl)methyl]-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, [(2-bromophenyl)methyl]-, diethyl ester(66192-11-8)
• EPA Substance Registry System: Propanedioic acid, [(2-bromophenyl)methyl]-, diethyl ester(66192-11-8)

Safety Data

• Hazardous Substances Data: 66192-11-8(Hazardous Substances Data)

Upstream product

• 95-46-5 2-methylphenyl bromide 
• 109-89-7 diethylamine 
• 6630-33-7 ortho-bromobenzaldehyde 
• 105-53-3 diethyl malonate 
• 93098-67-0 diethyl <(2-bromophenyl)methylene>propanedioate 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 

Downstream Products

• 91-20-3 naphthalene 
• 122951-09-1 1,3-dihydro-1-oxo-2H-indene-2,2-dicarboxylic acid diethyl ester 
• 93875-65-1 2-(1-Methyl-indanyl-⁽⁴⁾-formyl)-benzoesaeure 
• 93321-55-2 2-(Indanyl-⁽⁴⁾-formyl)-benzoesaeure 
• 857370-75-3 2-<1-Methyl-indanyl-(4)-methyl>-benzoesaeure 
• 93319-37-0 2--benzoesaeure 
• 63040-45-9 3,6-Dimethyl-2,3-dihydro-1H-cyclopentanthracen 
• 6134-53-8 4-bromo-2,3-dihydro-1H-indene 
• 110061-65-9 1-[2-(3-chloro-propyl)-phenyl]-1-hydroxy-1,2,3,4-tetrahydro-arsinolinium; chloride 
• 103281-42-1 1-bromo-2-(3-trityloxy-propyl)-benzene 
• 127620-00-2 (E)-Diethyl 1,2,3,4-tetrahydro-1-<(1-trimethylsilyl)-1-phenylmethylidene>naphthalene-3,3-dicarboxylate 
• 127619-99-2 (Z)-Diethyl 1,2,3,4-tetrahydro-1-(1-methyl-1-phenylmethylidene)naphthalene-3,3-dicarboxylate 
• 127619-98-1 (Z)-Diethyl 1,2,3,4-tetrahydro-1-(1-phenylmethylidene)naphthalene-3,3-dicarboxylate 
• 16657-07-1 4-bromo-3H-indene 

Relevant articles and documents

Light-Promoted Nickel Catalysis: Etherification of Aryl Electrophiles with Alcohols Catalyzed by a NiII-Aryl Complex

A highly effective C?O coupling reaction of (hetero)aryl electrophiles with primary and secondary alcohols is reported. Catalyzed by a NiII-aryl complex under long-wave UV (390–395 nm) irradiation in the presence of a soluble amine base without any additional photosensitizer, the reaction enables the etherification of aryl bromides and aryl chlorides as well as sulfonates with a wide range of primary and secondary aliphatic alcohols, affording synthetically important ethers. Intramolecular C?O coupling is also possible. The reaction appears to proceed via a NiI–NiIII catalytic cycle.

Pd-catalyzed desymmetric intramolecular O-arylation reaction: Enantioselective synthesis of (3,4-dihydro-2H-chromen-3-yl)methanols

An enantioselective intramolecular O-arylation was achieved through desymmetrization with Pd-catalyzed coupling reactions. The intramolecular asymmetric aryl C-O coupling reactions of 2-(2-haloaryl)propane-1,3-diols led to the enantioselective formation o

Catalytic generation and trapping of acylmetals containing Ni and Cu with enolates

Carbonylative cyclization of iodoarenes and iodoalkenes containing a proximal enolate precursor can selectively provide either cyclic ketones or lactones in the presence of Ni or Cu catalysts via trapping of putative acylmetal derivatives with C- or O-enolates, respectively; the ring size and regioselectivity of the reaction may be predicted based on two generalizations derived from the recently developed corresponding Pd-catalyzed reaction.