66236-14-4

Basic information

• Product Name: Methanesulfonamide, N-[4-chloro-2-(2-propenyl)phenyl]-
• CAS NO: 66236-14-4
• Molecular Formula: C10H12ClNO2S
• Molecular Weight: 245.73
• Mol File: 66236-14-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Methanesulfonamide, N-[4-chloro-2-(2-propenyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonamide, N-[4-chloro-2-(2-propenyl)phenyl]-(66236-14-4)
• EPA Substance Registry System: Methanesulfonamide, N-[4-chloro-2-(2-propenyl)phenyl]-(66236-14-4)

Safety Data

• Hazardous Substances Data: 66236-14-4(Hazardous Substances Data)

Upstream product

• 13519-80-7 N-allyl-4-chloroaniline 
• 106-47-8 4-chloro-aniline 
• 124-63-0 methanesulfonyl chloride 
• 267002-56-2 4-chloro-2-(prop-2-en-1-yl)aniline 

Relevant articles and documents

Synthesis of Benzofuran and Indole Derivatives Catalyzed by Palladium on Carbon

Benzofurans and indoles are key moieties in many natural products and pharmaceuticals. Herein, we describe a cheap and easy-to-execute strategy for the synthesis of benzofurans and indoles, employing Pd/C as the promoter. A variety of substituted allyl-anilines and allyl-phenols were converted into the desired products in good to excellent yields. Recycling of Pd/C was possible up to five cycles, keeping similar levels of reactivity.

Cu(oac)2-promoted cascade carboamination/oxidative cyclization of c-acylimines with alkenes

A Cu(OAc)2-promoted cascade carboamination/oxidative cyclization of alkenes with a-imino esters has been explored. This transformation provides a concise approach to rapid assembly of 2-oxo-3-iminopyrrole derivatives in moderate to good yields.