66241-44-9Relevant articles and documents
Metal-Catalyzed Organic Photoreactions. Bond-Cleavage Selectivity and Synthetic Application of the Iron(III) Chloride Catalyzed Photooxidation of Cyclic Olefins
Kohda, Akira,Nagayoshi, Kazuo,Maemoto, Kazuo,Sato, Tadashi
, p. 425 - 432 (2007/10/02)
Photooxidation of olefins in pyridine in the presence of iron(III) chloride produced either α-chloro ketones (type A), gem-dichloro ketones (type B), or α,ω-dichloro ketones (type C), depending upon the substitution pattern of the substrate olefin.The synthetic utility of the type B reaction was demonstrated by the synthesis of some natural products.The synthesis of optically active solanone from D-p-menthene confirmed the D configuration of the natural product.
Metal-Catalyzed Organic Photoreactions. One-Step Synthesis of Chlorinated Ketones from Olefins by Photooxidation in the Presence of Iron(III) Chloride
Kohda, Akira,Ueda, Keiko,,Sato, Tadashi
, p. 509 - 515 (2007/10/02)
Under photooxidation in pyridine in the presence of FeCl3, mono- and disubstituted olefins gave α-chloro ketones, while tri- and tetrasubstituted olefins gave dichloro ketones with a C-C bond cleavage.The reaction was interpreted in terms of an electron-transfer mechanism occurring within the coordination sphere of the iron ion
