66338-37-2Relevant articles and documents
Hydroformylation of recalcitrating biorenewable compounds containing trisubstituted double bonds
Faria, Amanda de Camargo,de Oliveira, Mileny P.,Monteiro, Amanda C.,Mota, Rayssa L.V.,Oliveira, Kelley C.B.,Santos, Eduardo N. dos,Gusevskaya, Elena V.
, (2020)
Hydroformylation is a useful tool in industrial organic syntheses and it is easily applied to substrates containing terminal C[sbnd]C double bonds. Applying this reaction to substrates containing other functionalities or trisubstituted C[sbnd]C double bonds is not straightforward. Herein, the hydroformylation of several biorenewable alkenes with these features, namely: α-terpineol, terpinen-4-ol, limonene (double hydroformylation), and α-ionone, is presented. Only by the judicious choice of the catalytic system and reaction conditions, was it possible to obtain good yields and selectivity for these substrates.