66348-47-8Relevant articles and documents
Synthesis of allylic and homoallylic alcohols from unsaturated cyclic ethers using a mild and selective C-O reduction approach
MacK, Daniel J.,Guo, Boying,Njardarson, Jon T.
, p. 7844 - 7846 (2012/09/05)
Unsaturated cyclic ethers can be mildly and selectively reduced with catalytic amounts of B(C6F5)3 in the presence of an alkylsilane. The allylic position is preferentially reduced with minimal or no scrambling of olefin geometry. For electronically equivalent substrates, steric factors guide the reducing agent to the least substituted site.
ORGANOMANGANESE (II) REAGENTS XVIII: COPPER-CATALYZED 1,4-ADDITION OF ORGANOMANGANESE CHLORIDE COMPOUNDS TO CONJUGATED ETHYLENIC ALDEHYDES.
Cahiez, Gerard,Alami, Mouad
, p. 7365 - 7368 (2007/10/02)
Organomanganese chlorides react with β-mono or β,β-bisubstituted α,β-ethylenic aldehydes in the presence of a catalytic amount of copper chloride to give good yields of 1,4-addition products in THF at -30 deg C.