66385-64-6

Basic information

• Product Name: Urea, N'-[2-(diphenylamino)ethyl]-N,N-diphenyl-
• CAS NO: 66385-64-6
• Molecular Formula: C27H25N3O
• Molecular Weight: 407.515
• Mol File: 66385-64-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Urea, N'-[2-(diphenylamino)ethyl]-N,N-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Urea, N'-[2-(diphenylamino)ethyl]-N,N-diphenyl-(66385-64-6)
• EPA Substance Registry System: Urea, N'-[2-(diphenylamino)ethyl]-N,N-diphenyl-(66385-64-6)

Safety Data

• Hazardous Substances Data: 66385-64-6(Hazardous Substances Data)

Upstream product

• 101-81-5 Diphenylmethane 
• 52204-95-2 N-(diphenylcarbamoyl)-aziridine 

Relevant articles and documents

Reactions with Azirridines, 36 Arene Hydrides 2 SN2 and SET Reactions of N-Acylaziridines with Diphenylmethanide and "Naphthalene Hydride" (Anion of Dihydronaphthalene)

Diphenylmethane is incompletely deprotonated by sodium naphthalenide in THF so that some "naphthalene hydride" 4 (anion of 1,4-dihydronaphthalene) remains present in the deprotonation equilibrium.The generated diphenylmethanide anion 3a reacts with the N-acylaziridines 6a-c to form the expected amidoethyl derivatives 7a-c in yields of less than 50percent.The formation of by-products from 6b and 6c can be rationalized on the basis of classic ionic mechanisms.However, for 6a the by-product N-ethylbenzamide clearly points to a SET mechanism with "naphthalene hydride" 4 as the electron source and with the radical 8 as a hydrogen source.