66502-11-2

Basic information

• Product Name: 2-isopropylsulfanyl-1-phenyl-ethanone
• Synonyms: 2-isopropylsulfanyl-1-phenyl-ethanone
• CAS NO: 66502-11-2
• Molecular Weight: 194.298
• Mol File: 66502-11-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-isopropylsulfanyl-1-phenyl-ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-isopropylsulfanyl-1-phenyl-ethanone(66502-11-2)
• EPA Substance Registry System: 2-isopropylsulfanyl-1-phenyl-ethanone(66502-11-2)

Safety Data

• Hazardous Substances Data: 66502-11-2(Hazardous Substances Data)

Upstream product

• 75-33-2 2-propanethiol 
• 70-11-1 α-bromoacetophenone 
• 3282-32-4 2-diazo-acetophenone 
• 532-27-4 1-chloroacetophenone 

Downstream Products

• 121045-44-1 3-(2-Acetoxy-1-isopropylsulfanyl-2-phenyl-ethyl)-4-hydroxy-benzoic acid ethyl ester 
• 121045-26-9 ethyl 2,3-dihydro-3-isopropylthio-2-phenyl-1-benzofuran-5-carboxylate 
• 121045-42-9 2-methoxyethyl 2-phenyl-1-benzofuran-5-carboxylate 
• 121045-39-4 5-methyl-2-phenylbenzofuran 
• 121045-19-0 2-isopropylthio-1-(2-methoxyethoxy)-1-phenylethane 
• 121045-17-8 1-acetoxy-1-phenyl-2-isopropylthioethane 
• 121045-40-7 2-phenyl-1-benzofuran-5-carbaldehyde 
• 14385-51-4 7-methoxy-2-phenylbenzo[b]furan 
• 7182-32-3 2-phenyl-5-methoxybenzo[b]furan 
• 50543-55-0 7-methyl-2-phenylbenzofuran 
• 18761-36-9 5-chloro-2-phenylbenzofuran 
• 25871-52-7 5-methyl-2-phenylbenzofuran 
• 59483-17-9 5,7-dimethyl-2-phenylbenzofuran 
• 121045-41-8 1-(2-phenyl-5-benzofuranyl)ethanone 

Relevant articles and documents

Highly chemoselective α-diazo carbonyl insertion reactions into N-H and S-H bonds catalysed by [RuCl(η5-C5H5)(PPh3)2]

Complex [RuCl(η5-C5H5)(PPh3)2], in chloroform at 60 deg C, catalyses the chemoselective insertion of α-diazo carbonyl compounds into N-H and S-H bonds to afford α-keto-amines and α-keto-thioethers.

SELECTIVE PREPARATION AND CYCLIZATION OF 2-(2-HYDROXYPHENYL)-2-(ISOPROPYLTHIO)ETHANOLS. NEW SYNTHESIS OF 1-BENZOFURANS

Reaction of phenols with 2-(isopropylthio)ethyl acetate activated by sulphuryl chloride afforded 2-phenols regioselectively, via sigmatropic rearrangement of phenoxysulphonium ylides.The ortho-alkylated phenols thus obtained have been cyclized with conc. hydrochloric acid in 2-methoxyethanol to 1-benzofurans. 2-Methyl- and 2-phenyl-1-benzofurans have been prepared similarly.