66530-00-5Relevant articles and documents
Nickel-Catalyzed Conjugate Addition of Alkynyl Groups to α,β-Unsaturated Ketones
Schwartz, Jeffrey,Carr, Denise B.,Hansen, Robert T.,Dayrit, Fabian M.
, p. 3053 - 3061 (1980)
The complex formed by reaction of Ni(acac)2 and DiBAH (1:1) catalyzes conjugate addition of dialkylaluminium acetylides to α,β enones; on hydrolysis, 3-alkynyl ketones are produced in high yield.Through this procedure conjugate addition of alkynyl groups