66605-77-4Relevant articles and documents
Novel phenolic antioxidant-functionalized dendritic polyethylene: Synthesis by tailor-made nickel(II) α-diimine-catalyzed copolymerization and its characteristics as non-releasing additive
Balzadeh, Zahra,Arabi, Hassan
, p. 68 - 78 (2017)
This work describes a simple one-pot and controlled synthetic method to generate migration-resistant bio-friendly tailor-made antioxidants through ethylene–sterically hindered phenolic antioxidant (SHPA) copolymerization by coordination polymerization usi
Photooxidation Kinetics in Heterogeneous Media
Clennan, Edward L.,Chen, Ming Fang
, p. 6004 - 6005 (1995)
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Metal-Free Activation of C-I Bonds and Perfluoroalkylation of Alkenes with Visible Light Using Phosphine Catalysts
Helmecke, Lucas,Spittler, Michael,Baumgarten, Kai,Czekelius, Constantin
supporting information, p. 7823 - 7827 (2019/10/11)
An efficient metal-free, photomediated iodo perfluoroalkylation under mild conditions was developed. Using catalytic amounts (10 mol %) of phosphines and blue light irradiation, various olefins are transformed into the corresponding addition products with
Branch-Selective Addition of Unactivated Olefins into Imines and Aldehydes
Matos, Jeishla L. M.,Vásquez-Céspedes, Suhelen,Gu, Jieyu,Oguma, Takuya,Shenvi, Ryan A.
supporting information, p. 16976 - 16981 (2019/01/04)
Radical hydrofunctionalization occurs with ease using metal-hydride hydrogen atom transfer (MHAT) catalysis to couple alkenes and competent radicalophilic electrophiles. Traditional two-electron electrophiles have remained unreactive. Herein we report the reductive coupling of electronically unbiased olefins with imines and aldehydes. Iron catalysis allows addition of alkyl-substituted olefins into imines through the intermediacy of free radicals, whereas a combination of catalytic Co(Salt-Bu,t-Bu) and chromium salts enables a branch-selective coupling of olefins and aldehydes through the formation of a putative alkyl chromium intermediate.