6662-92-6

Basic information

• Product Name: trityl N-tritylglycinate
• CAS NO: 6662-92-6
• Molecular Formula: C₁₆H₂₆O
• Molecular Weight: 559.6955
• Mol File: 6662-92-6.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 670.2°C at 760 mmHg
• Flash Point: 359.1°C
• Density: 1.16g/cm³
• Vapor Pressure: 7.96E-18mmHg at 25°C
• Refractive Index: 1.63
• CAS DataBase Reference: trityl N-tritylglycinate(CAS DataBase Reference)
• NIST Chemistry Reference: trityl N-tritylglycinate(6662-92-6)
• EPA Substance Registry System: trityl N-tritylglycinate(6662-92-6)

Safety Data

• Hazardous Substances Data: 6662-92-6(Hazardous Substances Data)

Upstream product

• 111-66-0 oct-1-ene 
• 30089-00-0 9-octyl-9-bora-bicyclo[3.3.1]nonane 
• 591-50-4 iodobenzene 
• 83698-31-1 2-Phenylacetyl-nonanoic acid methyl ester 
• 37779-49-0 methyl 3-oxo-4-phenylbutanoate 
• 629-04-9 1-Bromoheptane 
• 32508-91-1 1-phenyl-2-decanone 
• 122-78-1 phenylacetaldehyde 
• 143-15-7 1-dodecylbromide 

Downstream Products

• 124-19-6 nonan-1-al 

Relevant articles and documents

Nickel-Catalyzed Enantioselective Conjunctive Cross-Coupling of 9-BBN Borates

Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C?C bond forming reactions.

Transformation of Alkyl Halides to Aldehydes Having Two Additional Carbon Atoms

Methyl 3-oxo-4-phenylbutanoate (6) reacts with alkyl halides (1a-g) in the presence of NaH/benzene to furnish alkylated β-keto esters (2a-g).Hydrolysis of 2a-g gives benzyl ketones (3a-g), which on reduction with sodium borohydride give the homobenzylic alcohols (4a-g).The alcohols (4a-g) are readily fragmented to aldehydes (5a-g) on heating with lead tetraacetate/iodine.