66696-96-6

Basic information

• Product Name: 3-Oxo-tridec-12-enoic acid benzyl ester
• Synonyms: 3-Oxo-tridec-12-enoic acid benzyl ester
• CAS NO: 66696-96-6
• Molecular Weight: 316.441
• Mol File: 66696-96-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Oxo-tridec-12-enoic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxo-tridec-12-enoic acid benzyl ester(66696-96-6)
• EPA Substance Registry System: 3-Oxo-tridec-12-enoic acid benzyl ester(66696-96-6)

Safety Data

• Hazardous Substances Data: 66696-96-6(Hazardous Substances Data)

Upstream product

• 1286277-97-1 C₂₀H₂₆O₂ 
• 66696-83-1 5-(1-Hydroxy-undec-10-enylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione 
• 100-51-6 benzyl alcohol 

Relevant articles and documents

Oxone-promoted hydration of electron-deficient allenic esters and ketones into 1,3-dicarbonyl compounds

Abstract A novel and mild protocol for the hydration of electron-deficient allenic esters and ketones into various 1,3-dicarbonyl compounds is described. The hydration of allenes promoted by oxone in DMF afforded the corresponding products in moderate to good yields. This work features the employment of only a catalytic amount of inexpensive and nontoxic solid reagent oxone (2KHSO5·KHSO4·K2SO4), avoiding the utility of toxic metals or traditional Br?nsted acids, in a green version of viewpoint. A possible reaction mechanism for this transformation is also primarily proposed.