6682-69-5Relevant articles and documents
Leaving group effect on photochemistry of ortho-alkylphenacyl carboxylate
Kim, Seol Hee,Jang, Mi,Moon, Da Yoon,Park, Bong Ser
, p. 4245 - 4250 (2018/10/31)
-
Unique solvent effect on photochemistry of ortho-alkylphenacyl benzoates
Park, Bong Ser,Ryu, Hyuk Jun
scheme or table, p. 1512 - 1516 (2010/04/29)
Photolysis of 2,4,6-trialkylphenacyl benzoates gives not only the corresponding indanones and benzoic acid, but also the corresponding benzocyclobutenols (CBs), which are also detected in the photolysis of mono-alkylphenacyl benzoates for the first time.
Chromic Acid Oxidation of Indans and Tetralins to 1-Inadanones and 1-Tetralones Using Jones and Other Cr(VI) Reagents
Rangarajan, Radhika,Eisenbraun, E.J.
, p. 2435 - 2438 (2007/10/02)
The Jones chromic acid oxidation, ordinarily used for converting secondary alcohols to ketones, has been successfully extended to the oxidation of indans and tetralins to 1-indanones and 1-tetralones, respectively.A sixfold excess of the reagent was commonly used to ensure complete oxidation of starting material.Addition of anhydrous magnesium sulfate or oven-dried silica gel provided a yield increase of 15-20percent. 2,2'-Bipyridinium chlorochromate was also used and found to be effective in all cases, but this reagent requires a longer reaction time and a 16-fold excess.A comparison between these two reagents and CrO3 in acetic acid was made.The Jones reagent being least selective, gives the highest yield of sterically hindered monoketone from 1,2,3,4,5,6,7,8-octahydrophenanthrene.