6683-96-1

Basic information

• Product Name: 2-Octanone, 1-phenyl-
• CAS NO: 6683-96-1
• Molecular Formula: C14H20O
• Molecular Weight: 204.312
• Mol File: 6683-96-1.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 2-Octanone, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Octanone, 1-phenyl-(6683-96-1)
• EPA Substance Registry System: 2-Octanone, 1-phenyl-(6683-96-1)

Safety Data

• Hazardous Substances Data: 6683-96-1(Hazardous Substances Data)

Upstream product

• 19396-72-6 1-Phenyl-2-octanol 
• 1188-92-7 Trihexylboran; Tri-n-hexylbor 
• 536-74-3 phenylacetylene 
• 6691-72-1 n-Hexyl-benzyl-ketazin 
• 95110-66-0 2,3-epoxy-1-phenyl-2-phenylsulfinyloctane 
• 83698-30-0 1-Phenyl-3-carbomethoxy-2-octanone 
• 95110-72-8 1,2-epoxy-1-phenyl-2-phenylsulfinyloctane 
• 107967-87-3 1-Methyl-4-(2-methylsulfanyl-1-phenyl-octane-2-sulfonyl)-benzene 
• 81393-02-4 2-Benzyl-1-phenyl-octan-2-ol 
• 49845-69-4 (R)-O-acetylmandeloyl chloride 
• 3761-92-0 n-hexylmagnesium bromide 
• 16967-02-5 1-phenyl-1-octyne 
• 106-30-9 ethyl heptanoate 
• 6921-34-2 benzylmagnesium chloride 

Downstream Products

• 19396-72-6 1-Phenyl-2-octanol 
• 111-71-7 heptanal 

Relevant articles and documents

Ring size and nothing else matters: unusual regioselectivity of alkyne hydration by NHC gold(i) complexes

We have investigated the role of ring sizes and substituents in NHC ligands in some (NHC)Au(i) complexes in the hydration of internal alkynes. Despite the fact that using (NHC)Au(i) complexes in the hydration of diarylacetylenes leads to Markovnikov-type products, the precise tuning of ligands allows changing the regioselectivity in arylalkylacetylene hydration to the anti-Markovnikov-type.

NOVEL VINYLBENZENE COMPOUND AND PHOTOSENSITIVE PHOTORESIST COMPOSITION COMPRISING THE SAME

Provided is a photocurable composition comprising: (A) a photocurable compound; and (B) a vinylbenzene-containing monomer having a structure represented by chemical formula 1. In the chemical formula 1, X, R1, R2, R3, L, L1, L2 and L3 are the same as defi

Isolable gold(I) complexes having one low-coordinating ligand as catalysts for the selective hydration of substituted alkynes at room temperature without acidic promoters

Hydration of a wide range of alkynes to the corresponding ketones has been afforded in high yields at room temperature by using gold(I)-phosphine complexes as catalyst, with no acidic cocatalysts required. Suitable substrates covering alkyl and aryl terminal alkynes, enynes, internal alkynes, and propargylic alcohols, including enantiopure forms, are cleanly transformed to the corresponding ketones in nearly quantitative yields. Acid-labile groups present in the substrates are preserved. The catalytic activity strongly depends on both the nature of the phosphine coordinated to the gold (I) center and the softness of the counteranion, the complex AuSPhOsNTf2 showing the better activity. A plausible mechanism for the hydration of alkynes through ketal intermediates is proposed on the basis of kinetic studies. The described catalytic system should provide an efficient alternative to mercury-based methodologies and be useful in synthetic programs.