6689-37-8

Basic information

• Product Name: Silane, (2-methoxyphenoxy)trimethyl-
• CAS NO: 6689-37-8
• Molecular Formula: C10H16O2Si
• Molecular Weight: 196.321
• Mol File: 6689-37-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Silane, (2-methoxyphenoxy)trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (2-methoxyphenoxy)trimethyl-(6689-37-8)
• EPA Substance Registry System: Silane, (2-methoxyphenoxy)trimethyl-(6689-37-8)

Safety Data

• Hazardous Substances Data: 6689-37-8(Hazardous Substances Data)

Upstream product

• 5796-98-5 bis-trimethylsilanyl peroxide 
• 100-66-3 methoxybenzene 
• 25561-30-2 N,O-Bis(trimethylsilyl)trifluoroacetamide 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 90-05-1 2-methoxy-phenol 
• 10416-58-7 N,N-bis(trimethylsilyl)acetamide 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 75-77-4 chloro-trimethyl-silane 
• 13052-77-2 sodium 2-methoxyphenolate 

Downstream Products

• 90-05-1 2-methoxy-phenol 
• 7368-78-7 4-bromoguaiacol 
• 55482-89-8 Guaiaspir 
• 81674-79-5 2-methyl-2-<2-(methoxy)phenoxy>-4H-1,3-benzodioxin-4-one 

Relevant articles and documents

Regioselectivity of Hydroxyl Radical Reactions with Arenes in Nonaqueous Solutions

The regioselectivity of hydroxyl radical addition to arenes was studied using a novel analytical method capable of trapping radicals formed after the first elementary step of reaction, without alteration of the product distributions by secondary oxidation processes. Product analyses of these reactions indicate a preference for o- over p-substitution for electron donating groups, with both favored over m-addition. The observed distributions are qualitatively similar to those observed for the addition of other carbon-centered radicals, although the magnitude of the regioselectivity observed is greater for hydroxyl. The data, reproduced by high accuracy CBS-QB3 computational methods, indicate that both polar and radical stabilization effects play a role in the observed regioselectivities. The application and potential limitations of the analytical method used are discussed.

Enzymatic and nonenzymatic in vitro hydrolysis of 2-methyl-2-[2-(methoxy)phenoxy]-4H-1,3-benzodioxin-4-one and 2-methoxyphenyl O-acetylsalicylate

This paper is concerned with the synthesis and physical properties as well as the enzymatic and nonenzymatic in vitro hydrolysis of the potential aspirin prodrug MR 693 (5) and the salicylic acid prodrug guacetisalum (6). The half-lives of both prodrugs and the amount of aspirin regenerated in each hydrolytic run for 5 have been estimated over a wide range of pH values.

Electrophilic Hydroxylation with Bis(trimethylsilyl)peroxide. A Synthon for the Hydroxyl Cation

The regiospecific introduction of an hydroxy group in aromatic and aliphatic compounds can be performed in good yields by electrophilic hydroxylation of their organometallic derivatives with bis(trimethylsilyl)peroxide.