67248-39-9Relevant articles and documents
A new method for the preparation of fluoro-λ6-sulfanenitriles: Reaction of sulfimides with Selectfluor
Fujii, Takayoshi,Asai, Shinsuke,Okada, Tomoyuki,Hao, Wei,Morita, Hiroyuki,Yoshimura, Toshiaki
, p. 6203 - 6205 (2007/10/03)
Several diaryl(fluoro)-λ6-sulfanenitriles 3 were synthesized by the reaction of S,S-diarylsulfimides 1 with Selectfluor. This reaction also allows the first preparation of heterocyclic fluoro-λ6-sulfanenitrile, 5-fluoro-10,10-dioxo-5,10-dihydro-5λ6,10λ 6-thianthren-5-nitrile (5) and its molecular structure was determined by X-ray crystallographic analysis.
First Preparation and Reactions of S,S-Diaryl-S-fluorothiazynes, Ar2SF(N)
Yoshimura, Toshiaki,Kita, Hiroshi,Takeuchi, Kyu,Takata, Eiichi,Hasegawa, Kiyoshi,et al.
, p. 1433 - 1436 (2007/10/02)
S,S-Diaryl-S-fluorothiazynes, Ar2SF(N), were prepared by the reaction of S,S-diaryl-N-bromosulfilimines with tetrabutylammonium fluoride.The thiazyne structure was assigned by the spectral data, physical properties, and is consistent with reactions wit
