67249-03-0

Basic information

• Product Name: Benzoic acid, 4-[2-(4-bromophenyl)ethenyl]-, methyl ester
• CAS NO: 67249-03-0
• Molecular Formula: C16H13BrO2
• Molecular Weight: 317.182
• Mol File: 67249-03-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-[2-(4-bromophenyl)ethenyl]-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-[2-(4-bromophenyl)ethenyl]-, methyl ester(67249-03-0)
• EPA Substance Registry System: Benzoic acid, 4-[2-(4-bromophenyl)ethenyl]-, methyl ester(67249-03-0)

Safety Data

• Hazardous Substances Data: 67249-03-0(Hazardous Substances Data)

Upstream product

• 2417-72-3 Methyl 4-(bromomethyl)benzoate 
• 1122-91-4 4-bromo-benzaldehyde 
• 67-64-1 acetone 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 67-56-1 methanol 
• 1253-46-9 4-methoxycarbonylbenzyltriphenylphosphonium bromide 
• 38186-51-5 diethyl (4-bromobenzyl)phosphonate 
• 1571-08-0 methyl 4-formylbenzoate 
• 2039-82-9 1-bromo-4-ethenyl-benzene 

Downstream Products

• 666830-55-3 trans-4-(N,N-diphenylamino)-4'-(methoxycarbonyl)stilbene 
• 63483-64-7 4-p-Bromostyrylphenylessigsaeure 
• 700845-98-3 trans-4-(N,N-diphenylamino)-4'-(phthalimidomethyl)stilbene 
• 700845-97-2 trans-4-(N,N-diphenylamino)-4'-(hydroxymethyl)stilbene 

Relevant articles and documents

Rhodium-catalyzed oxidative decarbonylative Heck-type coupling of aromatic aldehydes with terminal alkenes

A rhodium-catalyzed oxidative decarbonylative Heck-type coupling of aromatic aldehydes with terminal alkenes to afford 1,2-disubstituted alkenes with good regio- and E-selectivity is developed. This reaction employs readily available aromatic aldehydes as the aryl electrophile counterpart and relies on selected acyl chloride as the crucial additive to activate the rhodium catalyst precursor.

Use of functionalized onium salts as a soluble support for organic synthesis

The invention relates to the use of a onium salt functionalized by at least one organic function, as a soluble support, in the presence of at least one organic solvent, for organic synthesis of a molecule, in a homogenous phase, by at least one transformation of said organic function. The onium salt enables the synthesized molecule to be released. The onium salt is present in liquid or solid form at room temperature and corresponds to formula A1+, X1?, wherein A1+ represents a cation and X1? represents an anion.