67262-98-0Relevant articles and documents
Influence of β-Silyl Groups in Cycloalkanones on the Norrish Type I and Type II Cleavages
Hwu, Jih Ru,Chen, Buh-Luen,Huang, Li Wen,Yang, Tu-Hsin
, p. 299 - 300 (1995)
The Norrish type I cleavage overwhelms the type II cleavage in the photolysis of α-alkylcycloalkanones bearing an SiMe3, SiMe2Ph, SiMePh2, or SiPh3 group at the β-position, of which the quantum yields are often greater than those of the non-silylated cycl
Chemistry and Composition of (Trialkylsilyl)cuprates Derived from Cuprous Halides
Sharma, Sunaina,Oehlschlager, Allan C.
, p. 5383 - 5387 (1989)
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Basic Copper Carbonate-Catalyzed Silyl Conjugate Additions to α,β-Unsaturated Carbonyls in Water
Wang, Wei,Li, Bo-Jie,Xiao, Zu-Feng,Yan, Feng,Wei, Peng-Ren,Wang, Lian-Sheng,Zhu, Lei
, p. 81 - 86 (2017/09/11)
We report here the silylation of α,β-unsaturated acceptors in water at room temperature using a copper catalyst. A broad substrate scope, including chalcone derivatives, esters, nitrile, and dienones, has been explored. In all cases, the reaction proceede
CuI-catalyzed conjugate addition of silyl boronic esters: Retracing catalytic cycles using isolated copper and boron enolate intermediates
Plotzitzka, Jacqueline,Kleeberg, Christian
, p. 6915 - 6926 (2015/02/05)
Copper(I)-catalyzed conjugate additions of silyl boronic esters to α,β-unsaturated aldehydes, ketones, and esters are synthetically well-established reactions. For the first time central reactive intermediates as well as the boron enolates as the primary
