67289-10-5

Basic information

• Product Name: Silane, [(2-bromo-1,4-phenylene)bis(oxy)]bis[trimethyl-
• CAS NO: 67289-10-5
• Molecular Formula: C12H21BrO2Si2
• Molecular Weight: 333.373
• Mol File: 67289-10-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, [(2-bromo-1,4-phenylene)bis(oxy)]bis[trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(2-bromo-1,4-phenylene)bis(oxy)]bis[trimethyl-(67289-10-5)
• EPA Substance Registry System: Silane, [(2-bromo-1,4-phenylene)bis(oxy)]bis[trimethyl-(67289-10-5)

Safety Data

• Hazardous Substances Data: 67289-10-5(Hazardous Substances Data)

Upstream product

• 123-31-9 hydroquinone 
• 75-77-4 chloro-trimethyl-silane 
• 583-69-7 2-bromobenzene-1,4-diol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 15288-57-0 2-trimethylsilyl-1,4-hydroquinone 
• 15288-54-7 2-(trimethylsilyl)-1,4-benzoquinone 

Relevant articles and documents

Trifluoromethanesulfonyloxy-group-directed regioselective (3 + 2) cycloadditions of benzynes for the synthesis of functionalized benzo-fused heterocycles

Highly regioselective (3 + 2) cycloadditions of (trifluoromethanesulfonyloxy)benzynes [(triflyloxy)benzynes] with 1,3-dipoles followed by cross-coupling reactions provided multisubstituted benzo-fused heterocycles. The triflyloxy group at the 3-position of benzynes, and even that at the remote 4-position, greatly affected the regiocontrol of the cycloaddition. These groups also served to install other substituents at their ipso-positions.