67399-73-9 Usage
General Description
Ethanone, 1-(2-thiazolidinyl)- (9CI) is a chemical compound with the formula C6H9NOS. It is a heterocyclic compound that contains a thiazolidine ring. This chemical is commonly used as a building block in organic synthesis, particularly in the development of pharmaceuticals and agrochemicals. It has been found to exhibit antibacterial and antifungal properties, making it an important component in the development of new drugs to combat microbial infections. Additionally, it has potential applications in the field of materials science, such as in the development of coatings and adhesives. Additionally, it is a potential ligand for metal coordination chemistry and is being studied for its potential use in catalysis and metal ion sensing.
Check Digit Verification of cas no
The CAS Registry Mumber 67399-73-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,7,3,9 and 9 respectively; the second part has 2 digits, 7 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 67399-73:
(7*6)+(6*7)+(5*3)+(4*9)+(3*9)+(2*7)+(1*3)=179
179 % 10 = 9
So 67399-73-9 is a valid CAS Registry Number.
InChI:InChI=1/C5H9NOS/c1-4(7)5-6-2-3-8-5/h5-6H,2-3H2,1H3
67399-73-9Relevant articles and documents
Regioselectivity of the hydrolysis of 2-(1-alkoxyvinyl)-substituted imidazolidines, 1,3-thiazolidines, and 1,3-oxazolidines
Keiko,Funtikova,Vchislo,Larina,Frolov
experimental part, p. 1832 - 1840 (2012/03/27)
2-(1-Alkoxyvinyl)-1,3-thiazolidines reacted with H2O or D 2O in the presence of 105 mol % of p-toluenesulfonic acid or trifluoroacetic acid (20°C, 1 h) to give 2-acetyl-1,3-thiazolidine in quantitative yield. 2-(1-Alkoxyvinyl)-3,5-diphenylimidazolidines underwent hydrolysis in the presence of 20 mol % of an acid (20°C, 24 h) at the vinyloxy group with high regioselectivity yielding 2-acetylimidazolidines. Hydrolysis of 2-(1-alkoxyvinyl)-3-phenyl-1,3-oxazolidines in the presence of 10 mol % of p-toluenesulfonic acid (20°C, 5 days) takes two pathways, one of which involves the endocyclic C-O bond with ring opening and the other involves the vinyloxy group to produce 2-acetyl-3-phenyl-1,3-oxazolidine. Unlike phenyl-substituted 1,3-thiazolidines and imidazolidines, hydrolysis of their 3-methyl- and 3,5-dimethyl-substituted analogs in acid medium occurs mainly via ring opening. The observed hydrolysis pathways were interpreted in terms of B3PW91/6-311G(d,p) quantum-chemical calculations.
