67431-17-8

Basic information

• Product Name: 1,4-Benzenediol, 2-methoxy-, 4-formate
• CAS NO: 67431-17-8
• Molecular Formula: C8H8O4
• Molecular Weight: 168.149
• Mol File: 67431-17-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,4-Benzenediol, 2-methoxy-, 4-formate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Benzenediol, 2-methoxy-, 4-formate(67431-17-8)
• EPA Substance Registry System: 1,4-Benzenediol, 2-methoxy-, 4-formate(67431-17-8)

Safety Data

• Hazardous Substances Data: 67431-17-8(Hazardous Substances Data)

Upstream product

• 121-33-5 vanillin 
• 218903-20-9 Formic acid 4-isopropoxy-3-methoxy-phenyl ester 

Downstream Products

• 824-46-4 methoxyhydroquinone 
• 945609-15-4 4-[(2E,6E,10E)-12-hydroxy-2,6,10-trimethyl-dodeca-2,6,10-trienyloxy]-3-methoxy-phenol 
• 218903-28-7 (4-Isopropoxy-2-methoxy-phenoxy)-triisopropyl-silane 
• 218903-27-6 3-methoxy-4-(triisopropylsiloxy)phenol 
• 218903-26-5 Formic acid 3-methoxy-4-triisopropylsilanyloxy-phenyl ester 

Relevant articles and documents

Synthesis of methoxyfumimycin with 1,2-addition to ketimines

(Chemical Equation Presented) The synthesis of (±)-methoxyfumimycin, a potential new bacterial peptide deformylase (PDF) inhibitor, is reported. To generate the stereogenic fully substituted carbon, the key step is a 1,2-addition of amethylGrignard reagent to a ketimine. The overall synthetic strategy involves a Dakin oxidation of a vanillin derivative, Friedel-Crafts acylation, Claisen rearrangement, lactonization, and rhodium-catalyzed olefin isomerization.

Selective cleavage of isopropyl aryl ethers by aluminum trichloride

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IMPROVED OXIDATION PROCEDURE WITH AROMATIC PEROXYACIDS

The application of the m-Chloroperbenzoic acid-potassium fluoride system in the Baeyer-Villinger oxidation of aromatic aldehydes and in the epoxidation of olefins has been studied.